A new synthetic route to metal trithiophosphonates:Syntheses and structures of [(C_6H_(11))PS_3Li_2-THF.TMEDA]_2 and [(C_6H_(11))PS_3Mg.2THF]_2

Jens K.Bjernemose; Robert P.Davies; Andrew P.S.Jurd

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A new synthetic route to metal trithiophosphonates:Syntheses and structures of [(C_6H_(11))PS_3Li_2-THF.TMEDA]_2 and [(C_6H_(11))PS_3Mg.2THF]_2

机译：金属三硫代膦酸酯的新合成途径：[（C_6H_（11））PS_3Li_2-THF.TMEDA] _2和[（C_6H_（11））PS_3Mg.2THF] _2的合成和结构

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A new synthesis for trithiophosphonates from primary phosphines,nBuLi(or nBu_2Mg)and elemental sulfur is presented and its mechanism investigated;the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.

机译：提出了一种由伯膦，nBuLi（或nBu_2Mg）和元素硫合成三硫代膦酸酯的新方法，并对其机理进行了研究;环己基三硫代膦酸酯的锂盐和镁盐已得到充分表征，可以揭示固态的二聚体，其中所有三种三硫代膦酸酯硫参与金属键合。

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《Dalton transactions: An international journal of inorganic chemistry》 |2004年第20期|共2页
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Jens K.Bjernemose; Robert P.Davies; Andrew P.S.Jurd;
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1. A new synthetic route to metal trithiophosphonates:Syntheses and structures of [(C_6H_(11))PS_3Li_2-THF.TMEDA]_2 and [(C_6H_(11))PS_3Mg.2THF]_2 [J] . Jens K.Bjernemose, Robert P.Davies, Andrew P.S.Jurd Dalton transactions: An international journal of inorganic chemistry . 2004,第20期

机译：金属三硫代膦酸酯的新合成途径：[（C_6H_（11））PS_3Li_2-THF.TMEDA] _2和[（C_6H_（11））PS_3Mg.2THF] _2的合成和结构
2. Synthesis and Physicochemical Properties of [{Cd(ε-C_6H_(11)NO)_5}_2Cr(NCS)_6] [Cd(ε-C_6H_(11)NO)_4Cr(NCS)_6] [J] . Yu. R. Giniyatullina, E. V. Peresypkina, A. V. Virovets Russian Journal of Inorganic Chemistry . 2012,第6期

机译：[{Cd（ε-C_6H_（11）NO）_5} _2Cr（NCS）_6] [Cd（ε-C_6H_（11）NO）_4Cr（NCS_6）的合成和理化性质
3. #epsilon#-Caprolactam as a Donor Ligand for Lanthanide Halides:Formation of Cationic [Ln(C_6H_(11)NO)_6Cl]~(2+) and [Ln(C_6H_(11)NO)_4 Cl_2]~+ Complexes [J] . William J.Evans, Cy H.Fujimoto, Michael A.Greci, European journal of inorganic chemistry . 2001,第3期

机译：＃epsilon＃-己内酰胺作为镧系元素卤化物的给体配体：阳离子[Ln（C_6H_（11）NO）_6Cl]〜（2+）和[Ln（C_6H_（11）NO）_4 Cl_2]〜+配合物的形成
4. Gallium Behavior in a Low-Temperature Molten Salt System C_6H_(11)N_2N(SO_2CF_3)_2 [C] . V. V. Smolenski, A. A. Khokhryakov, A. L. Bove, Topical Conference on Plutonium and Actinides . 2003

机译：低温熔盐系统中的镓行为C_6H_（11）N_2 n（SO_2CF_3）_2
5. Molecular Dynamic Simulations of {1122}{11 23} and {1121}{11 26} Twining Modes in Hexagonal Close-Packed Metals [D] . Ombogo, J. T. Maxwell 2018

机译：六角形密堆积金属中{1122} {11 23}和{1121} {11 26}的孪生模式的分子动力学模拟
6. Syntheses and crystal structures of the anhydride 4-oxatetracyclo5.3.2.026.0810dodec-11-ene-35-dione and the related imide 4-(4-bromophenyl)-4-azatetracyclo5.3.2.026.0810dodec-11-ene-35-dione [O] . Andrew Hulsman, Isabel Lorenzana, Theodore Schultz, 2020

机译：酸酐4-牛酸的合成和晶体结构5.3.2.026.0810 Dodec-11-Ene-35-二酮和相关酰亚胺4-（4-溴苯基）-4-α-azatetracyclo 5.3.2.02 6.0810 Dodec-11-Ene-35-二酮
7. (Dicyclohexylphosphino)borane, BH_3PH(C_6H_(11))_2, a Precursor to Water-Soluble Phosphine Ligands [O] . Day Michael W., Mohr Bernhard, Grubbs Robert H. 1996

机译：（二环己基膦基）硼烷BH_3PH（C_6H_（11））_ 2是水溶性膦配体的前体
8. Macrocycles Containing Tin. Two Syntheses of 1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-Tetrastannacycloeicosane and a Synthesis of 1,1,6,6-Tetraphenyl-1,6-Distannacyclodecane. [R] . Newcomb, M., Azuma, Y., Courtney, A. R. 1982

机译：含有锡的大环。两种合成1,1,6,6,11,11,16,16-八苯基-1,6,11,16-四氮杂环庚烷和1,1,6,6-四苯基-1,6-二炔基环十二烷的合成。

A new synthetic route to metal trithiophosphonates:Syntheses and structures of [(C_6H_(11))PS_3Li_2-THF.TMEDA]_2 and [(C_6H_(11))PS_3Mg.2THF]_2

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