New diamondoid-like [Cu_3B(μ-O)_6] core self-assembled from Bis-Tris biobuffer for mild hydrocarboxylation of alkanes to carboxylic acids

Kirillov A.M.; Karabach Y.Y.; Kirillova M.V.; Haukka M.; Pombeiro A.J.L.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >New diamondoid-like [Cu_3B(μ-O)_6] core self-assembled from Bis-Tris biobuffer for mild hydrocarboxylation of alkanes to carboxylic acids

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New diamondoid-like [Cu_3B(μ-O)_6] core self-assembled from Bis-Tris biobuffer for mild hydrocarboxylation of alkanes to carboxylic acids

机译：由Bis-Tris生物缓冲液自组装的新型类金刚石[Cu_3B（μ-O）_6]核，用于烷烃轻度加氢羧化成羧酸

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The new tricopper(ii) complex [Cu_3(μ_3-BO)(H _3L)_3][BF_4]·2H_2O (1) with an unprecedented diamondoid-like [Cu_3B(μ-O)_6] core has been easily generated by self-assembly in an aqueous medium from Cu(NO _3)_2, NaBF_4, NaOH and Bis-Tris (H_5L) biobuffer, (HOCH_2)_3CN(CH_2CH_2OH) _2. Compound 1 efficiently promotes the mild single-pot hydrocarboxylation, by CO and H_2O, of various linear and cyclic C_n (n = 2-8) alkanes into the corresponding C_(n+1) carboxylic acids.

机译：新型三铜（ii）络合物[Cu_3（μ_3-BO）（H _3L）_3] [BF_4]·2H_2O（1）具有前所未有的类金刚石样的[Cu_3B（μ-O）_6]核，很容易通过自身生成在水性介质中由Cu（NO _3）_2，NaBF_4，NaOH和Bis-Tris（H_5L）生物缓冲液（HOCH_2）_3CN（CH_2CH_2OH）_2组装。化合物1通过CO和H_2O有效地促进各种直链和环状C_n（n = 2-8）烷烃的温和的单锅加氢羧基化为相应的C_（n + 1）羧酸。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第24期|共4页
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Kirillov A.M.; Karabach Y.Y.; Kirillova M.V.; Haukka M.; Pombeiro A.J.L.;
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1. New diamondoid-like [Cu_3B(μ-O)_6] core self-assembled from Bis-Tris biobuffer for mild hydrocarboxylation of alkanes to carboxylic acids [J] . Kirillov A.M., Karabach Y.Y., Kirillova M.V., Dalton transactions: An international journal of inorganic chemistry . 2011,第24期

机译：由Bis-Tris生物缓冲液自组装的新型类金刚石[Cu_3B（μ-O）_6]核，用于烷烃轻度加氢羧化成羧酸
2. Topologically unique heterometallic Cu ~(II)/Li coordination polymers self-assembled from N, N-bis(2-hydroxyethyl)-2-aminoethanesulfonic acid biobuffer: Versatile catalyst precursors for mild hydrocarboxylation of alkanes to carboxylic acids [J] . Kirillova M.V., Kirillov A.M., Martins A.N.C., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第9期

机译：由N，N-双（2-羟乙基）-2-氨基乙烷磺酸生物缓冲剂自行组装的拓扑独特的杂金属Cu〜（II）/ Li配位聚合物：用于烷烃轻度加氢羧化为羧酸的多功能催化剂前体
3. Topologically unique heterometallic Cu ~(II)/Li coordination polymers self-assembled from N, N-bis(2-hydroxyethyl)-2-aminoethanesulfonic acid biobuffer: Versatile catalyst precursors for mild hydrocarboxylation of alkanes to carboxylic acids [J] . Kirillova M.V., Kirillov A.M., Martins A.N.C., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第9期

机译：由N，N-双（2-羟乙基）-2-氨基乙烷磺酸生物缓冲剂自行组装的拓扑独特的杂金属Cu〜（II）/ Li配位聚合物：用于烷烃轻度加氢羧化为羧酸的多功能催化剂前体
4. Carbonaceous material, alkanes, long-chain carboxylic acids and PAHs in PM10: concentration levels and sources in Rome [C] . P. Avino, D. Brocco, A. Cecinato Tenth International Conference on Modelling, Monitoring and Management of Air Pollution Jul, 2002 City of Segovia . 2002

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8. Orthogonal Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on Alumina. [R] . Laibinis, P. E., Whitesides, G. M., Hickman, J. J., 1989

机译：正交自组装单分子层：金属上的烷硫醇和氧化铝上的烷烃羧酸。

New diamondoid-like [Cu_3B(μ-O)_6] core self-assembled from Bis-Tris biobuffer for mild hydrocarboxylation of alkanes to carboxylic acids

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