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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Enhancement of quantum yield of LaPO_4:Ce~(3+):Tb ~(3+) nanocrystals by carbon nanotube induced suppression of the 1-dimensional growth
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Enhancement of quantum yield of LaPO_4:Ce~(3+):Tb ~(3+) nanocrystals by carbon nanotube induced suppression of the 1-dimensional growth

机译:碳纳米管诱导的一维生长抑制提高LaPO_4:Ce〜(3 +):Tb〜(3+)纳米晶体的量子产率

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摘要

Doped lanthanum phosphate nanocrystals are a class of fluorescent material of enormous interest, presenting an unusual dichotomy on the nanoscale. The quantum yields of these crystals drops significantly in the nanoscale when compared with the corresponding bulk yields. Herein we show that the suppression of their thermodynamically favored 1-D growth in the nanoscale results in an increase in the quantum yield. This is possible by inducing heterogeneous nucleation of the crystals on the surface of single walled carbon nanotubes.
机译:掺杂的磷酸镧纳米晶体是一类备受关注的荧光材料,在纳米级上呈现出不寻常的二分法。与相应的整体产率相比,这些晶体的量子产率在纳米级显着下降。在本文中,我们表明抑制它们的热力学有利于纳米级的1-D生长导致量子产率的增加。通过在单壁碳纳米管的表面上诱导晶体的异质成核,这是可能的。

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