Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels

Gu J.-M.; Kim W.-S.; Huh S.

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Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels

机译：具有一维通道的DABCO官能化Zn-MOF的尺寸依赖性催化

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Lewis basic DABCO-functionalized 3D-like metal-organic framework, Zn-MOF, catalyzes nitroaldol (Henry) reaction of 4-nitrobenzaldehyde with nitroalkanes in a size-dependent manner. Small nitroalkanes give rise to higher conversion than larger ones. This MOF-based heterogeneous catalyst is very robust and can be recycled several times without losing its activity.

机译：Lewis基本的DABCO官能化的3D样金属-有机骨架Zn-MOF以尺寸依赖的方式催化4-硝基苯甲醛与硝基烷的硝基羟醛（Henry）反应。小硝基烷比大硝基烷具有更高的转化率。这种基于MOF的非均相催化剂非常坚固，可以循环使用几次而不会失去其活性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第41期|共4页
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Gu J.-M.; Kim W.-S.; Huh S.;
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中图分类化学;
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1. Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels [J] . Gu J.-M., Kim W.-S., Huh S. Dalton transactions: An international journal of inorganic chemistry . 2011,第41期

机译：具有一维通道的DABCO官能化Zn-MOF的尺寸依赖性催化
2. Selective carbon dioxide sorption by a new breathing three-dimensional Zn-MOF with Lewis basic nitrogen-rich channels [J] . Kim Hyun-Chul, Huh Seong, Lee Do Nam, Dalton transactions: An international journal of inorganic chemistry . 2018,第14期

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6. Selective carbon dioxide sorption and heterogeneous catalysis by a new 3D Zn-MOF with nitrogen-rich 1D channels [O] . Hyun-Chul Kim, Seong Huh, Sung-Jin Kim, -1

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7. Unique size-dependent nanocatalysis revealed at the single atomically precise gold cluster level [O] . Yuwei Zhang, Ping Song, Tiankai Chen, 2018

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Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels

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