Metalloligands for designing single-molecule and single-chain magnets

Costes J.-P.; Vendier L.; Wernsdorfer W.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Metalloligands for designing single-molecule and single-chain magnets

【24h】

Metalloligands for designing single-molecule and single-chain magnets

机译：用于设计单分子和单链磁体的金属配体

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

2-Hydroxy-N-{2-[2-hydroxyethyl)amino]ethyl}benzamide (L~1H _3) and 2-hydroxy-N-{2-[2-hydroxybutyl)amino]ethyl}benzamide (L ~2H_3) ligands coordinate to copper ions to give anionic metalloligands, L~1Cu- and L~2Cu-, after deprotonation of their amide, alcohol and phenol functions. In presence of ancillary ligands as diketones, these metalloligands react with lanthanide salts to yield tetranuclear [Cu-Ln]_2 complexes while in presence of lanthanide salts alone, L~1Cu- gives 1D chains of tetranuclear entities linked through the Ln ions. The micro-SQUID data evidence the SMM behavior of the tetranuclear Tb complexes and the SCM behavior of the Tb chain derivative.

机译：2-羟基-N- {2- [2- [2-羟基乙基）氨基]乙基}苯甲酰胺（L〜1H _3）和2-羟基-N- {2- [2- [2-羟基丁基）氨基]乙基}苯甲酰胺（L〜2H_3）配体与铜离子配位后，会使其酰胺，醇和酚功能脱质子化，生成阴离子金属配体L〜1Cu-和L〜2Cu-。在存在作为二酮的辅助配体时，这些金属配体与镧系元素盐反应生成四核[Cu-Ln] _2配合物，而在单独存在镧系元素盐的情况下，L〜1Cu-给出通过Ln离子连接的四核实体的1D链。 micro-SQUID数据证明了四核Tb配合物的SMM行为和Tb链衍生物的SCM行为。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2010年第20期|共7页
作者
Costes J.-P.; Vendier L.; Wernsdorfer W.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Metalloligands for designing single-molecule and single-chain magnets [J] . Costes J.-P., Vendier L., Wernsdorfer W. Dalton transactions: An international journal of inorganic chemistry . 2010,第20期

机译：用于设计单分子和单链磁体的金属配体
2. Synthesis and Characterization of a Mn22 Single-Molecule Magnet and a [Mn22]_n Single-Chain Magnet [J] . Jonathan T. Brockman, Theocharis C. Stamatatos, Wolfgang Wernsdorfer Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第22期

机译：Mn22单分子磁体和[Mn22] _n单链磁体的合成与表征
3. [Mn_2~(III)(5-Rsaltmen)_2Ni~(II)(pao)_2(L)]~(2+):An S_T = 3 Building Block for a Single-Chain Magnet That Behaves as a Single-Molecule Magnet [J] . Hitoshi Miyasaka, Tomohiro Nezu, Ken-ichi Sugiura Chemistry: A European journal . 2005,第5期

机译：[Mn_2〜（III）（5-Rsaltmen）_2Ni〜（II）（pao）_2（L）]〜（2+）：作为单分子磁体的单链磁体的S_T = 3构建块
4. Single-chain magnet features in 1D MnR_4TPP TCNE compounds [C] . Maria Balanda, Zbigniew Tomkowicz, Wolfgang Haase Joint European Magnetic Symposia . 2010

机译：1D MNR_4TPP TCNE化合物中的单链磁铁功能
5. Directed Assembly of Single-Molecule and Single-Chain Magnets: From Mononuclear High- Spin Iron(II) Complexes to Cyano-Bridged Chain Compounds [D] . Harris, Thomas David, II 2010

机译：定向组装的单分子和单链磁体：从单核高自旋铁（II）配合物到氰桥链化合物。
6. Designing Single-Molecule Magnets as Drugs with Dual Anti-Inflammatory and Anti-Diabetic Effects [O] . Arturo Navas, Fatin Jannus, Belén Fernández, 2020

机译：设计具有抗炎和抗糖尿病双重作用的单分子磁体药物
7. Synthesis and Characterization of a Mn22 Single-Molecule Magnet and a Mn22n Single-Chain Magnet [O] . -1

机译：Mn22单分子磁体的合成与表征，Mn22 N单链磁铁

Metalloligands for designing single-molecule and single-chain magnets

摘要

著录项

相似文献

相关主题

期刊订阅