Transition metal alkynyl complexes by transmetallation from Au(C CAr)(PPh3) (Ar = C6H5 or C6H4Me-4)

Khairul WM; Fox MA; Zaitseva NN; Gaudio M; Yufit DS; Skelton BW; White AH; Howard JAK; Bruce MI; Low PJ

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Transition metal alkynyl complexes by transmetallation from Au(C CAr)(PPh3) (Ar = C6H5 or C6H4Me-4)

机译：通过Au（C CAr）（PPh3）（Ar = C6H5或C6H4Me-4）的金属转移作用过渡金属炔基配合物

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Facile acetylide transfer reactions take place between gold(I) complexes Au(C CAr)(PPh3) (Ar = C6H5 or C6H4Me-4) and a variety of representative inorganic and organometallic complexes MXLn (M = metal, X = halide, L-n = supporting ligands) featuring metals from groups 8-11, to afford the corresponding metal-alkynyl complexes M(C CR)L-n in modest to good yield. Reaction products have been characterised by spectroscopic methods, and molecular structure determinations are reported for Fe(C CC6H4Me-4)(dppe)Cp, Ru(C CC6H4Me-4)(dppe)Cp*, Ru(C CC6F5)(eta(2)-O-2)(PPh3)Cp*, Ir(C CC6H4Me-4)(eta(2)-O-2)(CO)(PPh3)(2), Ni(C CC6H4Me-4)(PPh3)Cp and trans-Pt(C CAr)(2)L-2 (Ar=C6H5, L=PPh3; Ar=C6H4Me-4, L=PPh3, PMe3).

机译：简便的乙炔化物转移反应在金（I）配合物Au（C CAr）（PPh3）（Ar = C6H5或C6H4Me-4）与多种代表性的无机和有机金属配合物MXLn（M =金属，X =卤化物，Ln = （支持配体）的特征为第8-11组的金属，以适度到良好的产率提供相应的金属-炔基配合物M（CCR）Ln。反应产物已通过分光光度法进行了表征，并报道了Fe（C CC6H4Me-4）（dppe）Cp，Ru（C CC6H4Me-4）（dppe）Cp *，Ru（C CC6F5）（eta（2）的分子结构测定）-O-2）（PPh3）Cp *，Ir（C CC6H4Me-4）（eta（2）-O-2）（CO）（PPh3）（2），Ni（C CC6H4Me-4）（PPh3）Cp和反式-Pt（C CAr）（2）L-2（Ar = C6H5，L = PPh3; Ar = C6H4Me-4，L = PPh3，PMe3）。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2009年第4期|共11页
作者
Khairul WM; Fox MA; Zaitseva NN; Gaudio M; Yufit DS; Skelton BW; White AH; Howard JAK; Bruce MI; Low PJ;
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正文语种 eng
中图分类无机化学;
关键词
X-RAY CRYSTAL; SIGMA-ACETYLIDE COMPLEXES; NONLINEAR-OPTICAL PROPERTIES; LIGAND-EXCHANGE REACTIONS; HIGHER CONJUGATED POLYYNES; MOLECULAR OXYGEN CARRIER; ELECTRONIC-STRUCTURES; OXIDATIVE ADDITION; CARBON CHAINS; COORDINATION ENVIRONMENT;

机译：X射线晶体;西格玛乙酰胺络合物;非线性光学性能;配体交换反应;高共轭多聚醚;分子氧载体;电子结构;氧化加成;碳链;配位环境;

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1. Transition metal alkynyl complexes by transmetallation from Au(C CAr)(PPh3) (Ar = C6H5 or C6H4Me-4) [J] . Khairul WM, Fox MA, Zaitseva NN, Dalton transactions: An international journal of inorganic chemistry . 2009,第4期

机译：通过Au（C CAr）（PPh3）（Ar = C6H5或C6H4Me-4）的金属转移作用过渡金属炔基配合物
2. Correction:Transition metal alkynyl complexes by transmetallation from Lambda u(C C)( PPh3) (Lambda r = C6H5 or C6H4Me-4) (pg 610, 2010) [J] . Khairul WM, Fox MA, Zaitseva NN, Dalton transactions: An international journal of inorganic chemistry . 2010,第47期

机译：校正：通过Lambda u（C C）（PPh3）的金属转移来过渡金属炔基配合物（Lambda r = C6H5或C6H4Me-4）（pg 610，2010）
3. Correction:Transition metal alkynyl complexes by transmetallation from Lambda u(C C)( PPh3) (Lambda r = C6H5 or C6H4Me-4) (pg 610, 2009) [J] . Khairul WM, Fox MA, Zaitseva NN, Dalton transactions: An international journal of inorganic chemistry . 2009,第47期

机译：校正：通过Lambda u（C C）（PPh3）的金属转移来过渡金属炔基配合物（Lambda r = C6H5或C6H4Me-4）（pg 610，2009）
4. 31P NMR STUDY OF AGⅠ-CUⅠ HETEROMETALLIC OCTA AND HEXADECANUCLEAR ALKYNYL COMPLEXES [C] . Xudong ZHANG, Ruiping CHEN, Qiaohua WEI, International Beijing Conference and Exhibition on Instrumental Analysis . 2007

机译：AGⅠ-CUⅠ异辛基和十六烷核炔基配合物的31P NMR研究
5. LATTICE ENERGY--DO PACKING FORCES AFFECT THE MOLECULAR CONFORMATIONS OF (I) M(-SC6H5)(4)(DINEGATIVE) (P(C6H5)(4))(2)(DIPOSITIVE) AND (II) AR(2)C = CAR(2)? [D] . SWENSON, DALE CARL. 1979

机译：晶格能量-做包装力影响（I）M（-SC6H5）（4）（可定性）（P（C6H5）（4））（2）（对数）和（II）AR（2）C的分子构象= CAR（2）？
6. Ex situ generation of stoichiometric HCN and its application in the Pd-catalysed cyanation of aryl bromides: evidence for a transmetallation step between two oxidative addition Pd-complexes [O] . Steffan K. Kristensen, Espen Z. Eikeland, Esben Taarning, 2017

机译：化学计量HCN的非原位生成及其在芳基溴化物的钯催化氰化中的应用：两个氧化加成钯复合物之间的过渡金属化步骤的证据
7. New gold(I) and silver(I) complexes with organophosphorus ligands with SPNSO skeleton. Crystal and molecular structures of monomeric Au{(SPPh2)(O2SR)N}(PPh3) (R = Me, C6H4Me-4) and dimeric Ag{(SPPh2)(O2SPh)N}(PPh3)2·2CH2Cl2 [O] . Pöllnitz Alpar, Silvestru Anca, Gimeno M. Concepción, 2012

机译：新的金（I）和银（I）与具有SPNSO骨架的有机磷配体配合。单体Au {（SPPh2）（O2SR）N}（PPh3）（R = Me，C6H4Me-4）和二聚体Ag {（SPPh2）（O2SPh）N}（PPh3） 2·2CH2Cl2的晶体和分子结构
8. Cluster Complex Metathesis. Synthesis, Structures, and Dynamic Behaviour of Bi- and Tri-Metallic Hexanuclear Cluster Complexes (MM'Ru4(millimicron3-H)2(CO)12(PPh3)2) (M ==M' == CU, Ag, or Au;M == CU, M' == Ag or Au; M == Ag, M' == [R] . Freeman, M. J., Green, M., Orphen, A. G., 1983

机译：簇复杂复分解。双金属和三金属六核簇合物（mm'Ru4（millimicron3-H）2（CO）12（pph3）2）（m == m'== CU，ag或au）的合成，结构和动态行为; m == CU，m'== ag或au; m == ag，m'==

Transition metal alkynyl complexes by transmetallation from Au(C CAr)(PPh3) (Ar = C6H5 or C6H4Me-4)

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