Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand

Subramanium S; Slaughter LM

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Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand

机译：直接观察与含双（N-杂环卡宾）配体的甲基钯羰基络合物中的CO /烯烃共聚有关的羰基化反应

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摘要

Use of a bulky bidentate bis(NHC) ligand allows isolation of a stable cationic methylpalladium carbonyl complex that undergoes clean carbonylation to an acyl complex under excess CO, modeling a key step in CO/alkene copolymerization.

机译：使用大体积的双齿双（NHC）配体可以分离出稳定的阳离子甲基钯羰基络合物，该络合物在过量的CO下经过干净的羰基化反应形成酰基络合物，从而模拟了CO /烯烃共聚合的关键步骤。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第35期|共4页
作者
Subramanium S; Slaughter LM;
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正文语种 eng
中图分类化学;
关键词
N-HETEROCYCLIC CARBENES; CATALYZED ALTERNATING COPOLYMERIZATION; MIGRATORY INSERTION REACTIONS;

机译：N-杂环;催化交替共聚;迁移插入反应;

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1. Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand [J] . Subramanium S, Slaughter LM Dalton transactions: An international journal of inorganic chemistry . 2009,第35期

机译：直接观察与含双（N-杂环卡宾）配体的甲基钯羰基络合物中的CO /烯烃共聚有关的羰基化反应
2. Reaction of CO with a methylpalladium heterocyclic carbene complex: Product decomposition routes-implications for catalytic carbonylation processes [J] . McGuinness DS., Cavell KJ. Organometallics . 2000,第23期

机译：CO与甲基钯杂环卡宾配合物的反应：产物分解途径-催化羰基化过程的意义
3. Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands [J] . Dirk Meyer, Thomas Strassner Beilstein journal of organic chemistry. . 2016,第1期

机译：具有嘧啶官能化的N-杂环卡宾配体的甲基钯配合物
4. Ni(0)-Catalyzed Coupling Reaction of 1,3-Diene and Carbonyl Compound Using N-Heterocyclic Carbene as a Ligand [C] . Rieko Sawaki, Yoshihiro Sato, Miwako Mori Symposium on Organometallic Chemistry . 2003

机译：Ni（0） - 使用N-杂环碳化物作为配体的1,3-二烯和羰基化合物的催化反应
5. Synthesis and luminescence of organometallic complexes. Part I: Rhenium(I) carbonyl complexes and their ligands in anion recognition. Part II: Chiral ferrocenyl-substituted N-heterocyclic carbene ligands [D] . Odago, Maurice Otieno 2010

机译：有机金属配合物的合成和发光。第一部分：R（I）羰基配合物及其配体在阴离子识别中的作用。第二部分：手性二茂铁基取代的N-杂环卡宾配体
6. Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands [O] . Dirk Meyer, Thomas Strassner 2016

机译：具有嘧啶官能化的N-杂环卡宾配体的甲基钯配合物
7. Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands [O] . Dirk Meyer, Thomas Strassner 2016

机译：甲基钯与嘧啶官能化的N-杂环卡宾配体络合
8. Dialkylamino Phosphorus Metal Carbonyls. 2. Bis(diisopropylamino)phosphido and (Diisopropylamino)phosphinidene Metal Carbonyl Complexes from Reactions of Manganese and Cobalt Carbonyls with Bis(diisopropylamino)phosphine [R] . King, R. B., Fu, W. K., Holt, E. M. 1986

机译：二烷基氨基磷酸金属羰基化合物。 2.来自锰和羰基钴与双（二异丙基氨基）膦的反应的双（二异丙基氨基）膦基和（二异丙基氨基）亚膦基金属羰基配合物

Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand

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