One-and two-photon excited dual fluorescence properties of zinc(II)and cadmium(II)complexes containing 4-dipropylaminobenzaldehyde thiosemicarbazone

Zhao-Ming Xue; Yu-Peng Tian; Dong Wang; Min-Hua Jiang

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One-and two-photon excited dual fluorescence properties of zinc(II)and cadmium(II)complexes containing 4-dipropylaminobenzaldehyde thiosemicarbazone

机译：含4-二丙基氨基苯甲醛硫半脲的锌（II）和镉（II）配合物的单光子和双光子激发的双荧光性质

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A new ligand,4-dipropylaminobenzaldehyde thiosemicarbazone(HL)and its complexes(ZnL_2,CdL_2),which exhibit intense two-photon excited(TPE)dual fluorescence using 800 nm laser pulses in the femtosecond regime,were synthesized and fully characterized.The measured power dependence of the fluorescence signals provides direct evidence for TPE.The two-photon excited dual fluorescence spectra were compared and contrasted with the corresponding results obtained from one-photon excitation.Emission peaks of the ligand and its complexes were assigned with the aid of PM3 calculations.

机译：合成并充分表征了一种新的配体4-二丙基氨基苯甲醛硫代半碳酮（HL）及其配合物（ZnL_2，CdL_2），其在飞秒状态下使用800 nm激光脉冲表现出强的双光子激发（TPE）双荧光。荧光信号的功率依赖性为TPE提供了直接的证据。将双光子激发的双荧光光谱与单光子激发获得的相应结果进行比较和对比。借助PM3来确定配体及其配合物的发射峰计算。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第7期|共6页
作者
Zhao-Ming Xue; Yu-Peng Tian; Dong Wang; Min-Hua Jiang;
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1. One-and two-photon excited dual fluorescence properties of zinc(II)and cadmium(II)complexes containing 4-dipropylaminobenzaldehyde thiosemicarbazone [J] . Zhao-Ming Xue, Yu-Peng Tian, Dong Wang, Dalton transactions: An international journal of inorganic chemistry . 2003,第7期

机译：含4-二丙基氨基苯甲醛硫半脲的锌（II）和镉（II）配合物的单光子和双光子激发的双荧光性质
2. Two-photon-excited fluorescence of zinc(II), cadmium (II) complexes containing phenothiazine ligand [J] . XUE Zhaoming, TIAN Yupeng, WANG Dong, Science in China. Series B, Chemistry . 2003,第5期

机译：含吩噻嗪配体的锌（II），镉（II）配合物的双光子激发荧光
3. Synthesis, crystal structure, characterization of zinc(II), cadmium(II) complexes with 3-thiophene aldehyde thiosemicarbazone (3TTSCH). Biological activities of 3TTSCH and its complexes [J] . Kusai Alomar, Anne Landreau, Anne Landreau, Journal of Inorganic Biochemistry: An Interdisciplinary Journal . 2010,第4期

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4. Preparation and Fluorescence Properties of Dendritic 8-HydroxyquinoIine and Their Zinc Complexes [C] . Xihuai Qiang, Yanjiao Wang, Hui Zhang International Conference on Chemical Engineering and Advanced Materials . 2011

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7. Synthesis, crystal structure, characterization of zinc(II), cadmium(II) complexes with 3-thiophene aldehyde thiosemicarbazone (3TTSCH). Biological activities of 3TTSCH and its complexes [O] . K. Alomar, A. Landreau, M. Kempf, 2010

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One-and two-photon excited dual fluorescence properties of zinc(II)and cadmium(II)complexes containing 4-dipropylaminobenzaldehyde thiosemicarbazone

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