The first polyoxoalkoxovanadium germanate anion with a novel cage-like structure:solvothermal synthesis and characterization

Yan-Min Chen; En-Bo Wang; Bi-Zhou Lin; Shu-Tao Wang

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The first polyoxoalkoxovanadium germanate anion with a novel cage-like structure:solvothermal synthesis and characterization

机译：第一种具有新型笼状结构的聚氧代烷氧钒锗酸根阴离子：溶剂热合成与表征

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The first example of polyoxoalkoxovanadium germanate,(NH_4)_2[H_3V_9Ge_6O_26(L)_6] centre dot 0.65H_2O(H_2L = HOCH_2CH_2OH),was solvothermally synthesized,and its polyanion is made up of six VO_6 octahedra,three VO_5 square pyramids and six GeO_4 tctrahedra with six bridging ethylene glycol ligands projecting outwards from the central core.Because of the rich variety of their components,structures,and properties,significant attention continues to be focused on polyoxometallic anions in many research fields.Poly-oxometalates with organic oxygen-donor groups show an impressive structural and electronic diversity,and extensive synthetic research has been carried out in this field over the past few years.The incorporated ligands include alkoxides,acetals,organophosphonates,organoarsonates,etc.

机译：溶剂热合成锗酸多氧烷氧钒钒的第一个例子（NH_4）_2 [H_3V_9Ge_6O_26（L）_6]中心点0.65H_2O（H_2L = HOCH_2CH_2OH），其聚阴离子由六个VO_6八面体，三个VO_5方形金字塔组成tctrahedra具有从中心核心向外突出的六个桥联乙二醇配体。由于其组成，结构和性质的多样性，在许多研究领域中，人们继续将注意力集中在多金属氧阴离子上。含有机氧供体的多金属氧酸盐这些基团显示出令人印象深刻的结构和电子多样性，并且在过去几年中已经在该领域进行了广泛的合成研究。引入的配体包括醇盐，缩醛，有机膦酸酯，有机organ酸酯等。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第4期|共2页
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Yan-Min Chen; En-Bo Wang; Bi-Zhou Lin; Shu-Tao Wang;
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1. The first polyoxoalkoxovanadium germanate anion with a novel cage-like structure:solvothermal synthesis and characterization [J] . Yan-Min Chen, En-Bo Wang, Bi-Zhou Lin, Dalton transactions: An international journal of inorganic chemistry . 2003,第4期

机译：第一种具有新型笼状结构的聚氧代烷氧钒锗酸根阴离子：溶剂热合成与表征
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机译：含有机胺配体的锗酸锌：Zn_2Ge_4O _（10）（NH_2CH_2CH_2CH_2NH _2）和ZnGe_2O_5（NH_2CH _2CH_2NH_2）的溶剂热合成及结构表征
3. The structure directing effect of organic cations onto the crystal structures of layered thioantimonates(III): Solvothermal synthesis and crystal structures of five new compounds containing the (infinity)~2[Sb_8Si_(13)]~(2-) anion [J] . Angela Puls, Christian Nather, Ragnar Kiebach Solid state sciences . 2006,第9期

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4. Synthesis and Characterization of Cage-like Nanostructures [C] . Young-Woong Suh, Wenmei Xue, Mayfair C. Kung International Symposium on Runaway Reactions, Pressure Relief Design and Effluent Handling American Institute of Chemical Engineers/American Chemical Society Management Conference . 2005

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The first polyoxoalkoxovanadium germanate anion with a novel cage-like structure:solvothermal synthesis and characterization

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