Interaction of ammonia borane with Li2NH and Li3N

Xiong ZT; Chua YS; Wu GT; Wang L; Wong MW; Kam ZM; Autrey T; Kemmitt T; Chen P

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Interaction of ammonia borane with Li2NH and Li3N

机译：氨硼烷与Li2NH和Li3N的相互作用

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摘要

Interaction of NH3BH3 and Li2NH (or Li3N) in THF leads to the formation of NH3 and LiNH2BH3, which further react with each other and produce ca. 10 wt.% hydrogen at 45 degrees C.

机译：NH3BH3和Li2NH（或Li3N）在THF中的相互作用导致NH3和LiNH2BH3的形成，它们进一步相互反应并生成大约2。在45摄氏度时含10 wt。％的氢。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2010年第3期|共3页
作者
Xiong ZT; Chua YS; Wu GT; Wang L; Wong MW; Kam ZM; Autrey T; Kemmitt T; Chen P;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
HYDROGEN STORAGE; AMIDOBORANES; LITHIUM;

机译：氢存储;氨基硼烷;锂;

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1. Interaction of ammonia borane with Li2NH and Li3N [J] . Xiong ZT, Chua YS, Wu GT, Dalton transactions: An international journal of inorganic chemistry . 2010,第3期

机译：氨硼烷与Li2NH和Li3N的相互作用
2. Syntheses and Structural Characterizations of Anionic Borane-Capped Ammonia Borane Oligomers: Evidence for Ammonia Borane H_2 Release via a Base-Promoted Anionic Dehydropolymerization Mechanism [J] . William C. Ewing, Allegra Marchione, Daniel W. Himmelberger, Journal of the American Chemical Society . 2011,第42期

机译：阴离子硼烷封端的氨硼烷低聚物的合成和结构表征：氨硼烷H_2通过碱促进的阴离子脱氢机理释放的证据
3. High-performance solid catalysts for H2 generation from ammonia borane: progress through synergetic Cu-Ni interactions [J] . Hoang Yen, Freddy Kleitz Journal of Materials Chemistry, A. Materials for energy and sustainability . 2013,第46期

机译：由氨硼烷生成氢气的高性能固体催化剂：通过协同作用的Cu-Ni相互作用而取得的进展
4. Ammonia Borane Dehydrogenation Always Generates Ammonia, How Much and How to Remove It? [C] . Ahmad Al-Kukhun, Hyun Tae Hwang, Arvind Varma AIChE annual meeting . 2010

机译：氨硼烷脱氢总是产生氨，多少氨以及如何去除氨？
5. Dehydrogenation and Phase Transition Properties of Ammonia Borane-Polyethylene Oxide Composites [D] . Kharel, Krishna. 2018

机译：氨基硼烷 - 聚环氧丙烷复合材料的脱氢和相变性能
6. Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate B-(cyclotriborazanyl)amine-borane [O] . Hassan A. Kalviri, Felix Gärtner, Gang Ye, 2015

机译：探索氨-硼烷脱氢偶联反应中的第二个脱氢步骤：关键中间体B-（环三氮杂硼烷基）胺-硼烷的表征和反应性
7. Highly efficient hydrolysis of ammonia borane by anion (-OH, F-, Cl-)-tuned interactions between reactant molecules and CoP nanoparticles [O] . Fu ZC, Xu Y, Chan SLF, 2017

机译：阴离子（-OH，F-，Cl-）调节的反应物分子与CoP纳米颗粒之间的相互作用对氨硼烷的高效水解
8. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes. Final Report [R] . Hawthorne, M. F., Jalisatgi, S. S., Safronov, A. V., 2010

机译：使用多面体硼烷阴离子和铝 - 氨 - 硼烷配合物的化学氢储存。总结报告

Interaction of ammonia borane with Li2NH and Li3N

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