A mixed valence manganese triangle in a trigonal lattice: Structure and magnetism

Taleb N.; Richards V.J.; Argent S.P.; Van Slageren J.; Lewis W.; Blake A.J.; Champness N.R.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >A mixed valence manganese triangle in a trigonal lattice: Structure and magnetism

【24h】

A mixed valence manganese triangle in a trigonal lattice: Structure and magnetism

机译：三角晶格中的混合价锰三角：结构和磁性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The synthesis, structural and magnetic characterisation of trinuclear manganese cluster, [Mn_3O(O_2C-anth)_6(HOCH _3)_3] _1 (where O2C-anth = 9- anthracenecarboxylate), with crystallographic three-fold (C_3) symmetry, are described. The cluster was prepared by a carboxylate exchange reaction between HO2C-anth and [Mn_(12)O_(12)(O _2CMe)_(16)(H_2O_)4] with concomitant fragmentation of the dodecanuclear Mn core of the starting material to form a trinuclear Mn_3(μ~3-O) cluster capped by six carboxylate ligands. Bond valence sum calculations and SQUID magnetometric measurements establish the oxidation states of the metal ions as MnII·2 MnIII which are antiferromagnetically coupled.

机译：描述了三核锰簇[Mn_3O（O_2C-蒽）_6（HOCH _3）_3] _1（其中O2C-蒽= 9-蒽羧酸盐）的合成，结构和磁性表征，具有晶体学三重（C_3）对称性。。通过HO2C-蒽与[Mn_（12）O_（12）（O _2CMe）_（16）（H_2O_）4]之间的羧酸酯交换反应以及起始材料的十二烷核锰核的碎裂来制备簇三核Mn_3（μ〜3-O）簇，由六个羧酸盐配体封端。键价和计算和SQUID磁力测量确定了反铁磁耦合的金属离子MnII·2 MnIII的氧化态。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2011年第22期|共4页
作者
Taleb N.; Richards V.J.; Argent S.P.; Van Slageren J.; Lewis W.; Blake A.J.; Champness N.R.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. A mixed valence manganese triangle in a trigonal lattice: Structure and magnetism [J] . Taleb N., Richards V.J., Argent S.P., Dalton transactions: An international journal of inorganic chemistry . 2011,第22期

机译：三角晶格中的混合价锰三角：结构和磁性
2. Trapping of a Pseudotetrahedral (CoO4)-O-II Core in Mixed-Valence Mixed-Geometry [Co-5] Coordination Aggregates: Synthetic Marvel, Structures, and Magnetism [J] . Chattopadhyay Krishna, Ojea Maria Jose Heras, Sarkar Arup, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第21期

机译：在混合价混合 - 几何形状[CO-5]协调聚集体中捕获假氮（COO4）-O-II核：合成辐射，结构和磁力
3. Trapping of a Pseudotetrahedral (CoO4)-O-II Core in Mixed-Valence Mixed-Geometry [Co-5] Coordination Aggregates: Synthetic Marvel, Structures, and Magnetism [J] . Chattopadhyay Krishna, Ojea Maria Jose Heras, Sarkar Arup, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第21期

机译：在混合价混合 - 几何形状[CO-5]协调聚集体中捕获假氮（COO4）-O-II核：合成辐射，结构和磁力
4. Unique Behavior of Lattice Modulation Phase Induced by Ligand Motion of a Mixed-Valence Metal-Halogen Complex [C] . International conference on ultrafast phenomena topical meeting and tabletop exhibit . 2006

机译：用混合价金属 - 卤素复合物的配体运动诱导的晶格调制相的独特行为
5. Magnetism and mixed valence in europium compounds under pressure. [D] . Di Marzio, Donald. 1987

机译：压力下euro化合物的磁性和混合化合价。
6. Magnetism in Mixed Valence Defect Cubic Perovskites: BaIn [O] . AntonioD. Lozano-Gorrín, Bradley Wright, Paul A. Dube, 2021

机译：混合价磁性缺陷立方佩洛夫斯基斯：贝恩
7. Synthesis and characterization of mixed-valence manganese fluorophosphate and analogues with clathrate-like structures: MnIII6F12(PO3(OH))8Na8(Kx(H3O)4−x(H2O)2)MIV(OH)6 (MIV = Mn, Ti, Ge) [O] . Wei-Jian Ren, Jing-Quan Wang, Ya-Xi Huang, 2015

机译：混合价氟磷酸氟磷酸盐的合成与表征用克拉酸盐状结构：MnIII6F12（PO 3（OH））8 Na8（KN（H3O）4-x（H2O）2）MiV（OH）6（MIV = Mn ，ti，ge）
8. Magnetism of Mixed Valence Compounds [R] . Hatfield, W. E. 1979

机译：混合价化合物的磁性

A mixed valence manganese triangle in a trigonal lattice: Structure and magnetism

摘要

著录项

相似文献

相关主题

期刊订阅