Studies of the isomerization and photophysical properties of a novel 2,2′:6′,2′′-terpyridine-based ligand and its complexes

Li D.; Zhang Q.; Wang P.; Wu J.; Kan Y.; Tian Y.; Zhou H.; Yang J.; Tao X.; Jiang M.

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Studies of the isomerization and photophysical properties of a novel 2,2′:6′,2′′-terpyridine-based ligand and its complexes

机译：基于2,2'：6'，2''-三联吡啶的新型配体及其配合物的异构化和光物理性质的研究

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A novel 2,2′:6′,2′′-terpyridine-based ligand L and its complexes [ML_2](ClO_4)_2·CH _2Cl_2 (M = Cd 1, Zn 2, Cu 4, Mn 5), [CoL _2](ClO_4)_23, CdLI_26 and CdL(SCN) _27 were synthesized and fully characterized. The crystal structures of 1-6 were solved by single crystal X-ray diffraction analysis. The linear absorption and emission properties, and third-order nonlinear optical (NLO) properties of all the complexes were systematically investigated. The equilibrium of the trans- and cis- isomers of L was studied both experimentally and theoretically. The configurations and photophysical properties of the complexes display a large dependence on the choice of metal ions and anions.

机译：一种新型的2,2'：6'，2''-基于吡啶的配体L及其配合物[ML_2]（ClO_4）_2·CH _2Cl_2（M = Cd 1，Zn 2，Cu 4，Mn 5），[CoL合成了_2]（ClO_4）_23，CdLI_26和CdL（SCN）_27。通过单晶X射线衍射分析来解析1-6的晶体结构。系统地研究了所有配合物的线性吸收和发射性质以及三阶非线性光学性质。通过实验和理论研究了L的反式和顺式异构体的平衡。配合物的构型和光物理性质对金属离子和阴离子的选择显示出很大的依赖性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第32期|共9页
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Li D.; Zhang Q.; Wang P.; Wu J.; Kan Y.; Tian Y.; Zhou H.; Yang J.; Tao X.; Jiang M.;
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1. Studies of the isomerization and photophysical properties of a novel 2,2′:6′,2′′-terpyridine-based ligand and its complexes [J] . Li D., Zhang Q., Wang P., Dalton transactions: An international journal of inorganic chemistry . 2011,第32期

机译：基于2,2'：6'，2''-三联吡啶的新型配体及其配合物的异构化和光物理性质的研究
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Studies of the isomerization and photophysical properties of a novel 2,2′:6′,2′′-terpyridine-based ligand and its complexes

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