A novel Mn-containing conducting metallopolymer obtained by electropolymerization in aqueous solution of a tetranuclear oxo-bridged manganese complex

Martin C.S.; Teixeira M.F.S.

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A novel Mn-containing conducting metallopolymer obtained by electropolymerization in aqueous solution of a tetranuclear oxo-bridged manganese complex

机译：通过在四核氧桥联锰配合物的水溶液中电聚合获得的新型含锰导电金属聚合物

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The [Mn_4IVO_5(terpy)_4(H _2O)_2]~(6+) complex shows great potential for electrode modification by electropolymerization using cyclic voltammetry. The electropolymerization mechanism was based on the electron transfer between dx~2-y~2 orbitals of the metallic center and pπ orbital of the ligand.

机译：[Mn_4IVO_5（terpy）_4（H _2O）_2]〜（6+）配合物显示出通过循环伏安法通过电聚合进行电极修饰的巨大潜力。电聚合机理是基于金属中心的dx〜2-y〜2轨道与配体的pπ轨道之间的电子转移。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第27期|共4页
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Martin C.S.; Teixeira M.F.S.;
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1. A novel Mn-containing conducting metallopolymer obtained by electropolymerization in aqueous solution of a tetranuclear oxo-bridged manganese complex [J] . Martin C.S., Teixeira M.F.S. Dalton transactions: An international journal of inorganic chemistry . 2011,第27期

机译：通过在四核氧桥联锰配合物的水溶液中电聚合获得的新型含锰导电金属聚合物
2. A comparison of charge-transfer mechanisms at rotated disk electrode for biomimetic binuclear and tetranuclear oxo-manganese complex in aqueous solution [J] . Martin Cibely S., Teixeira Marcos F. S. Inorganica Chimica Acta . 2015,第Null期

机译：仿生双核和四核氧锰配合物水溶液中旋转圆盘电极上电荷转移机理的比较
3. Electrochemical Interconversion of Mono-, Bi-, and Tetranuclear (Bipyridyl) Manganese Complexes in Buffered Aqueous Solution [J] . Marie-Noelle Collomb Dunand-Sauthier, Alain Deronzier, Xavier Pradon Journal of the American Chemical Society . 1997,第13期

机译：缓冲水溶液中单核，双核和四核（联吡啶）锰配合物的电化学转化
4. Electropolymerization Mechanism in Aqueous Solution of the Oxo-Manganese Complex Biomimicking of the Enzymatic Center Present on the Photosystem II [C] . C. S. Martin, M. F. S. Teixeira Simposio Brasileiro de Eletroquimica e Eletroanalitica . 2012

机译：在照相中存在的酶中心的氧代锰复合物生物捣蛋水溶液中的电聚合机理
5. Characterization of tetranuclear manganese complexes and thermochromic copper(II) and nickel(II) complexes. [D] . Schmitt, Edward Albert. 1995

机译：四核锰配合物和热致变色铜（II）和镍（II）配合物的表征。
6. The Mn Cluster in the S0 State of the Oxygen-Evolving Complex of Photosystem II Studied by EXAFS Spectroscopy: Are There Three Di-μ-oxo-bridged Mn2 Moieties in the Tetranuclear Mn Complex? [O] . John H. Robblee, Johannes Messinger, Roehl M. Cinco, -1

机译：通过EXAFS光谱研究光系统II的析氧配合物的S0态中的Mn团簇：四核Mn配合物中是否存在三个Di-μ-氧代桥联的Mn2部分？
7. A novel Mn-containing conducting metallopolymer obtained by electropolymerization in aqueous solution of a tetranuclear oxo-bridged manganese complex [O] . Martin, Cibely S. [UNESP], Teixeira, Marcos F. S. [UNESP] 2011

机译：通过在四核氧桥联锰配合物的水溶液中电聚合获得的新型含锰导电金属聚合物

A novel Mn-containing conducting metallopolymer obtained by electropolymerization in aqueous solution of a tetranuclear oxo-bridged manganese complex

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