Cytotoxic gold(i)-bearing dendrimers from alkyne precursors

Robilotto T.J.; Alt D.S.; Von Recum H.A.; Gray T.G.

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Cytotoxic gold(i)-bearing dendrimers from alkyne precursors

机译：来自炔烃前体的具有细胞毒性的金（i）树状大分子

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A series of four dendrimers end-functionalized with gold(i) has been prepared from alkyne-terminated precursors and (tricyclohexylphosphine)gold(i) azide. Isolated yields range from 84-89%, based on gold. The first-generation dendrimer is cytotoxic toward 3T3 mouse fibroblast cells. Apoptosis ensues within 6 h of treatment with gold(i).

机译：从炔基封端的前体和叠氮化金（i）制备了一系列四个用金（i）末端官能化的树枝状聚合物。按金计算，单独的收益率范围为84-89％。第一代树状聚合物对3T3小鼠成纤维细胞具有细胞毒性。在用金（i）处理后6小时内发生凋亡。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第32期|共3页
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Robilotto T.J.; Alt D.S.; Von Recum H.A.; Gray T.G.;
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专利

1. Cytotoxic gold(i)-bearing dendrimers from alkyne precursors [J] . Robilotto T.J., Alt D.S., Von Recum H.A., Dalton transactions: An international journal of inorganic chemistry . 2011,第32期

机译：来自炔烃前体的具有细胞毒性的金（i）树状大分子
2. Preparation and Orthogonal Postmodification of Dual-Clickable Polymer Precursors Bearing Both Aldehyde and Alkyne Groups [J] . Lin Lvhuan, Huang Jianbing, Ma Zhian, Journal of Polymer Science, Part A. Polymer Chemistry . 2017,第16期

机译：携带醛和炔基的双击聚合物前体的制备和正交过修
3. Half-sandwich (η~6-arene)iron(II) dinitrogen complexes bearing a disilaferracycle skeleton as a precursor for double silylation of ethylene and alkynes [J] . Sunada Y., Imaoka T., Nagashima H. Organometallics . 2010,第23期

机译：带有二硅铁环骨架的半三明治（η〜6-芳烃）铁（II）二氮配合物作为乙烯和炔烃双硅烷化的前体
4. Probing Gold-Catalyzed Alkyne Hydration Reaction by Mass Spectrometry: Evidence for Dinuclear Gold Intermediates [C] . Mei Lu, Yijin Su, Yumeng Xi, ASMS Conference on Mass Spectrometry and Allied Topics . 2014

机译：质谱法探测金催化的炔烃水合反应：二核金中间体的证据
5. Exploration of the chemistry of alkynes and Selectfluor. Search for cytotoxic agents from the Amazonian rainforest [D] . Jin, Zhuang 2012

机译：探索炔烃和Selectfluor的化学。从亚马逊雨林中寻找细胞毒剂
6. A Cationic Gold(I) Complex as a General Catalyst for the Intermolecular Hydroamination of Alkynes. Application to the One-Pot Synthesis of Allenes from Two Alkynes and a Sacrificial Amine [O] . Xiaoming Zeng, Guido D. Frey, Shazia Kousar, -1

机译：阳离子金（I）配合物作为炔烃分子间加氢胺化反应的一般催化剂。由两个炔烃和一种牺牲胺一锅法合成烯丙基的应用
7. Cationic gold(I) heteroleptic complexes bearing a pyrazole-derived N-heterocyclic carbene: syntheses, characterizations, and cytotoxic activities [O] . Sivaram Haresh, Tan Jackie, Huynh Han Vinh 2013

机译：带有吡唑衍生的N-杂环卡宾的阳离子金（I）杂合剂配合物：合成，表征和细胞毒活性
8. Preparation and Characterization of Dendrimer Monolayers and Dendrimer-AlkylthiolMixed Monolayers Adsorbed to Gold [R] . Tokuhisa, H., Zhao, M., Baker, L., 1998

机译：树枝状大分子单体和树枝状大分子 - 烷基硫醇混合单分子层吸附金的制备与表征

Cytotoxic gold(i)-bearing dendrimers from alkyne precursors

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