SCS-pincer palladium-catalyzed auto-tandem catalysis using dendritic catalysts in semi-permeable compartments

Pijnenburg N.J.M.; Dijkstra H.P.; Van Koten G.; Gebbink R.J.M.K.

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SCS-pincer palladium-catalyzed auto-tandem catalysis using dendritic catalysts in semi-permeable compartments

机译：使用半渗透性隔室中的树枝状催化剂的SCS-pincer钯钯自动串联催化

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Novel monometallic and dendritic SCS-pincer palladium complexes 2, 3 and 4 have been synthesized in good yields (60-89%) and high purity (palladium loading >97%). These complexes were successfully used as catalysts in the stannylation of cinnamyl chloride with hexamethylditin and in the catalytic auto-tandem reaction consisting of this stannylation followed by an electrophilic addition with 4-nitrobenzaldehyde, showing similar reaction rates and selectivities for all complexes. Dendritic complex 4 has furthermore been used in the compartmentalized catalysis of single and auto-tandem reactions, allowing catalyst reuse for four consecutive runs.

机译：新型单金属和树枝状SCS-pincer钯配合物2、3和4已以高收率（60-89％）和高纯度（钯载量> 97％）合成。这些配合物已成功地用作肉桂酰氯与六甲基二锡的甲锡化反应的催化剂，以及由这种甲锡化反应与4-硝基苯甲醛进行亲电加成反应组成的催化自动串联反应的催化剂，对所有配合物显示出相似的反应速率和选择性。此外，树枝状复合物4已用于单反应和自动串联反应的区室催化中，使催化剂可重复使用四次。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第35期|共10页
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Pijnenburg N.J.M.; Dijkstra H.P.; Van Koten G.; Gebbink R.J.M.K.;
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1. SCS-pincer palladium-catalyzed auto-tandem catalysis using dendritic catalysts in semi-permeable compartments [J] . Pijnenburg N.J.M., Dijkstra H.P., Van Koten G., Dalton transactions: An international journal of inorganic chemistry . 2011,第35期

机译：使用半渗透性隔室中的树枝状催化剂的SCS-pincer钯钯自动串联催化
2. Auto-Tandem Catalysis in Ionic Liquids: Synthesis of 2-Oxazolidinones by Palladium-Catalyzed Oxidative Carbonylation of Propargylic Amines in EmimEtSO(4) [J] . Mancuso Raffaella, Maner Asif, Ziccarelli Ida, Molecules . 2016,第7期

机译：离子液体中的自动串联催化：EmimEtSO中钯催化的炔丙基胺的氧化羰基化反应合成2-恶唑烷酮（4）
3. Auto-tandem catalysis: Synthesis of substituted 11H-indolo [3,2-c]quinolines via palladium-catalyzed intermolecular C-N and intramolecular C-C bond formation [J] . Meyers C, Rornbouts G, Loones KTJ, Advanced synthesis & catalysis . 2008,第3期

机译：自动串联催化：通过钯催化的分子间C-N和分子内C-C键的形成来合成取代的11H-吲哚并[3,2-c]喹啉
4. DESIGN OF CATALYSTS AND CATALYST LIBRARIES Computational Techniques in High Throughput Experimentation for Catalysis [C] . J. M. NEWSAM NATO advanced study institute on combinatorial catalysis and high throughput catalyst design and testing . 2000

机译：催化剂和催化剂文库催化试验中的催化剂和催化剂文库计算技术
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Auto-Tandem Catalysis in Ionic Liquids: Synthesis of 2-Oxazolidinones by Palladium-Catalyzed Oxidative Carbonylation of Propargylic Amines in EmimEtSO4 [O] . Raffaella Mancuso, Asif Maner, Ida Ziccarelli, 2016

机译：离子液体中的自动串联催化：在EmimEtSO4中钯催化的炔丙基胺的氧化羰基化反应合成2-恶唑烷酮
7. Auto-Tandem Catalysis in Ionic Liquids: Synthesis of 2-Oxazolidinones by Palladium-Catalyzed Oxidative Carbonylation of Propargylic Amines in EmimEtSO4 [O] . Mancuso, Raffaella, Maner, Asif, Ziccarelli, Ida, 2016

机译：离子液体中的自动串联催化：在EmimEtSO4中钯催化的炔丙基胺的氧化羰基化反应合成2-恶唑烷酮

SCS-pincer palladium-catalyzed auto-tandem catalysis using dendritic catalysts in semi-permeable compartments

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