Ruthenium-catalyzed oxidation of a carbon-carbon triple bond: Facile syntheses of alkenyl 1,2-diketones from alkynes

Hu T.-C.; Hsiao P.-I.; Wang T.-H.; Yang Y.-W.; Chang C.-Y.; Wu Y.-H.; Sun W.-C.; Yu M.-S.; Lee C.-Y.; Lo Y.-H.

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Ruthenium-catalyzed oxidation of a carbon-carbon triple bond: Facile syntheses of alkenyl 1,2-diketones from alkynes

机译：钌催化的碳-碳三键氧化：从炔烃中轻松合成烯基1,2-二酮

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A new oxidation procedure of alkynes catalyzed by Tp(PPh _3)(CH_3CN)Ru-Cl is presented, which provides an efficient way to obtain alkenyl 1,2-diketones via ruthenium alkenyl 1,2-diketone intermediates. In contrast, the analogous reactions with Tp(PPh _3)(PhCN)Ru-Cl gave rise to the ruthenium metallacycle complexes.

机译：提出了一种新的由Tp（PPh _3）（CH_3CN）Ru-Cl催化的炔烃氧化方法，为通过钌烯基1,2-二酮中间体获得烯基1,2-二酮提供了一种有效的方法。相反，与Tp（PPh _3）（PhCN）Ru-Cl的类似反应产生了钌金属环配合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第47期|共4页
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Hu T.-C.; Hsiao P.-I.; Wang T.-H.; Yang Y.-W.; Chang C.-Y.; Wu Y.-H.; Sun W.-C.; Yu M.-S.; Lee C.-Y.; Lo Y.-H.;
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1. Ruthenium-catalyzed oxidation of a carbon-carbon triple bond: Facile syntheses of alkenyl 1,2-diketones from alkynes [J] . Hu T.-C., Hsiao P.-I., Wang T.-H., Dalton transactions: An international journal of inorganic chemistry . 2011,第47期

机译：钌催化的碳-碳三键氧化：从炔烃中轻松合成烯基1,2-二酮
2. Cobalt(Ⅱ) catalyzed C(sp)-H bond functionalization of alkynes with phenyl hydrazines: facile access to diaryl 1,2-diketones [J] . Jaideep B. Bharate, Sheenu Abbat, Rohit Sharma, Organic & biomolecular chemistry . 2015,第18期

机译：钴（Ⅱ）催化炔烃与苯基肼的C（sp）-H键官能化：容易获得二芳基1,2-二酮
3. 2-Iodoxybenzoic acid mediated facile conversion of 1,3-diols to 1,2-diketones by oxidative cleavage of the C-C bond [J] . Yadav JS, Biswas SK, Srinivas R Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2006,第24期

机译：2-碘氧基苯甲酸通过C-C键的氧化裂解介导的1,3-二醇向1,2-二酮的轻松转化
4. Ruthenium-Catalyzed Coupling Reaction of Aromatic Compounds with Alkenyl Acetates via Regioselective C-H Bond Cleavage [C] . Fumitoshi Kakiuchi, Masaru Tamura, Takuya Kochi Symposium on Organometallic Chemistry . 2008

机译：芳族催化芳族化合物通过区域选择性C-H键裂解芳族化合物与链烯基的偶联反应
5. THE ACTIVATION OF ALKYNES TOWARD CARBON-CARBON BOND FORMATION AND CARBON-CARBON BOND CLEAVAGE IN THEIR REACTIONS WITH TUNGSTEN(2)(OR)(6)L(X) COMPOUNDS [D] . CONROY, BRIAN K. 1987

机译：钨（2）（或）（6）L（X）化合物反应中烷基向碳-碳键形成的活化和碳-碳键的裂解
6. A Ruthenium-Catalyzed Coupling of Alkynes with 13-Diketones [O] . Megan K. Pennington-Boggio, Brian L. Conley, Travis J. Williams -1

机译：alkynes含有13-二酮的钌催化偶联
7. Ruthenium-Catalyzed Transformation of Aryl and Alkynyl Propargyl Ethers into Aryl and Alkynyl Ketones via Cleavage of a Carbon-Carbon Triple Bond [O] . -1

机译：钌催化芳基和炔基炔丙基醚通过裂解碳 - 碳三键转化为芳基和炔基酮的转化
8. Reactions of Metal-Metal Multiple Bonds. 8. Forming Mo-Mo Quadruple Bonds by Reductive Elimination (Alkyl Group Disproportionation) in the Reactions of 1,2-Mo2R2(NMe2)4 Compounds (M triple bond M) with Carbon Dioxide and 1,3-Diary [R] . Chisholm, M. H., Folting, K., Haitko, D. A., 1981

机译：金属 - 金属多重键的反应。 8.通过还原消除（烷基基团歧化）在1,2-mo2R2（Nme2）4化合物（m三键m）与二氧化碳和1,3-日本的反应中形成mo-mo四键

Ruthenium-catalyzed oxidation of a carbon-carbon triple bond: Facile syntheses of alkenyl 1,2-diketones from alkynes

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