A novel polyoxochromium borophosphate with new 6-membered ring crown-shaped clusters

Liu W.; Zhang L.; Su G.; Cao L.-X.; Wang Y.-G.

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A novel polyoxochromium borophosphate with new 6-membered ring crown-shaped clusters

机译：一种新型的具有六元环冠状簇的新型多氧铬酸硼磷盐

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A novel chromium borophosphate with anionic clusters has been synthesized using boric acid as flux. X-ray diffraction analysis on a single crystal reveals that its structure comprises of crown-shaped 6-membered ring clusters [NaCr_8B_4P_(12)O_(60)H_8] ~(15-), which are built from [Cr_4O_(18)] groups, [BP_2O_(10)] anions and PO_4 tetrahedra with Na ~+ cations encapsulated in the clusters. Magnetic investigation showed strong antiferromagnetic interactions between Cr~(3+)-Cr~(3+) dimers at low temperature.

机译：以硼酸为助熔剂，合成了具有阴离子簇的新型硼硼酸铬。在单晶上进行X射线衍射分析表明，其结构由冠状6元环簇[NaCr_8B_4P_（12）O_（60）H_8]〜（15-）组成，它们是由[Cr_4O_（18）]构建的。基团，[BP_2O_（10）]阴离子和PO_4四面体，其中Na〜+阳离子包裹在簇中。磁性研究表明，低温下Cr〜（3 +）-Cr〜（3+）二聚体之间有很强的反铁磁相互作用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2010年第31期|共4页
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Liu W.; Zhang L.; Su G.; Cao L.-X.; Wang Y.-G.;
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1. A novel polyoxochromium borophosphate with new 6-membered ring crown-shaped clusters [J] . Liu W., Zhang L., Su G., Dalton transactions: An international journal of inorganic chemistry . 2010,第31期

机译：一种新型的具有六元环冠状簇的新型多氧铬酸硼磷盐
2. QTAIM Analysis of Ligand Properties and Mechanisms of Tuning of 6-Membered Ring N-Heterocyclic Carbenes in Transition Metal Complexes through Ring-Substituent Variation [J] . Lucius E. Johnson, Donald B. DuPre The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2009,第30期

机译：QTAIM分析配体性质和通过环取代基变化调节过渡金属配合物中6元环N-杂环卡宾的机理
3. Why ketonization is favored over enolization in 5-membered ring H-transfers by CH3C(=OH+)CH2C degrees H-2 and in 6-membered ring H-transfers by CH3(C=OH+)CH2CH2C degrees H-2 [J] . Hudson CE, Varela L, Griffin LL, International journal of mass spectrometry . 2006,第0期

机译：为什么在CH3C（= OH +）CH2C度H-2的5元环H-转移和CH3（C = OH +）CH2CH2C度H-2的6元环H-转移中酮化优于烯醇化
4. Stereoselective synthesis of 5-and 6-membered cyclic beta-amino acids [C] . Patrick Perlmutter, Mark Rose, Filisaty Vounatsos European Peptide Symposium . 2002

机译：立体选择合成5-和6元环β-氨基酸
5. Enantioselective synthesis and reactivity of bicyclobutanes: Strained molecular platforms for 4-, 5-, and 6-membered ring synthesis and rhodium(II)-catalyzed reactions of diazoesters with organozinc reagents. [D] . Panish, Robert A. 2016

机译：双环丁烷的对映选择性合成和反应性：重氮化合物与有机锌试剂的4元，5元和6元环合成和铑（II）催化反应的应变分子平台。
6. Synthetic Strategies for 5- and 6-Membered Ring Azaheterocycles Facilitated by Iminyl Radicals [O] . John C. Walton 2016

机译：亚胺基自由基促进的5元和6元环氮杂杂环的合成策略
7. Synthetic strategies for 5- and 6-membered ring azaheterocycles facilitated by iminyl radicals [O] . Walton, John Christopher 2016

机译：亚胺基促进的5元和6元环氮杂杂环的合成策略
8. Ion Exchange in Fused Salts. Iii. The Cation Exchange Characteristics of Some Borate, Borosilicate, and Borophosphate Glasses in Fused Sodium Nitrate [R] . Rowell, M. H. 1966

机译：熔盐中的离子交换。三。熔融硝酸钠中硼酸盐，硼硅酸盐和硼磷酸盐玻璃的阳离子交换特性

A novel polyoxochromium borophosphate with new 6-membered ring crown-shaped clusters

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