Strained organosilacyclic compounds: Synthesis of anti-Bredt olefins and trans-dioxasilacyclooctenes

Prévost M.; Ziller J.W.; Woerpel K.A.

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Strained organosilacyclic compounds: Synthesis of anti-Bredt olefins and trans-dioxasilacyclooctenes

机译：应变的有机硅环化合物：反布雷德烯烃和反式-二氧杂硅烷基环辛烯的合成

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Insertions of silylenes into the allylic carbon-oxygen bond of vinyl epoxides was shown to generate 1,2-silaoxetanes. These intermediates undergo highly diastereoselective additions to aldehydes to form anti-Bredt olefins and trans-dioxasilacyclooctenes. Additions of electrophiles could be performed selectively on the outside face of these strained trans-cycloalkenes to provide valuable functionalized compounds.

机译：显示出将亚甲硅烷基插入乙烯基环氧化物的烯丙基碳-氧键中会生成1,2-硅氧杂环丁烷。这些中间体经过高度非对映选择性地加成醛，形成抗Bredt烯烃和反式二氧杂硅烷基环辛烯。可以在这些应变的反式环烯烃的外表面选择性地进行亲电试剂的添加，以提供有价值的官能化化合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2010年第39期|共7页
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Prévost M.; Ziller J.W.; Woerpel K.A.;
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1. Strained organosilacyclic compounds: Synthesis of anti-Bredt olefins and trans-dioxasilacyclooctenes [J] . Prévost M., Ziller J.W., Woerpel K.A. Dalton transactions: An international journal of inorganic chemistry . 2010,第39期

机译：应变的有机硅环化合物：反布雷德烯烃和反式-二氧杂硅烷基环辛烯的合成
2. Synthesis of an Anti-Bredt Compound, Bicyclo[3.2.2]nona-1,6,8-triene, via the Isomerization of Tricyclo[3.2.2.0~(2,4)]nona-2,6-diene [J] . Gon-Ann Lee, Hung-Chun Lin Organic letters . 2014,第20期

机译：通过三环[3.2.2.0〜（2,4）] nona-2,6-二烯的异构化反应合成抗Bredt化合物双环[3.2.2] nona-1,6,8-三烯
3. Rhodium(III)-catalyzed ring-opening of strained olefins through C-H activation of O-acetyl ketoximes: an efficient synthesis of trans-functionalized cyclopentenes and spiro[2.4]heptenes [J] . E. Jijy, Praveen Prakash, M. Shimi Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2013,第52期

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5. Synthesis of strained ring compounds: Precursors to disilyne via molecular beam method [D] . Pichaandi, Kothanda Rama 2008

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机译：钯催化通过引导的64-palladacycle催化β-羟基化合物的合成来自指向的C-H抗苯胺和C-O的环氧化物的C-O.
7. Publisher’s Note: Synthesis ofα′′−Fe16N2Compound Anisotropic Magnet by the Strained-Wire Method Phys. Rev. Applied6, 024013 (2016) [O] . Yanfeng Jiang, Vivekanand Dabade, Lawrence F. Allard, 2016

机译：发行商注意：应变丝法合成α' - FE16N2组分各向异性磁铁题。 Applied6,024013（2016）

Strained organosilacyclic compounds: Synthesis of anti-Bredt olefins and trans-dioxasilacyclooctenes

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