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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Mechanochromism of Ag~i complexes with iPrNHC(S)NHP(S)(OiPr) _2
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Mechanochromism of Ag~i complexes with iPrNHC(S)NHP(S)(OiPr) _2

机译:Ag〜i与iPrNHC(S)NHP(S)(OiPr)_2配合物的机械变色

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摘要

Reaction of the potassium salt of iPrNHC(S)NHP(S)(OiPr)_2 (HL) with AgPF_6 leads to the hexanuclear [{Ag_3(iPrNHC(S)NP(S) (OiPr)_2-S,S′)_3}_2] ([(Ag_3L _3)_2]) complex. The reversible conversion between yellow-emitting ([(Ag_3L_3)_2]) and blue-emitting ([Ag_3L_3]) materials on grinding and recrystallization was established. [Ag_3L_3] was also prepared by a mechanically induced solid-state reaction.
机译:iPrNHC(S)NHP(S)(OiPr)_2(HL)与AgPF_6的钾盐反应生成六核[{Ag_3(iPrNHC(S)NP(S)(OiPr)_2-S,S')_ 3 } _2]([(Ag_3L _3)_2])复合体。建立了在研磨和重结晶时发黄光的[[(Ag_3L_3)_2]]和发蓝光的[[Ag_3L_3]]之间的可逆转换。 [Ag_3L_3]也通过机械诱导的固态反应制备。

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