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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions
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Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions

机译：描述使用金属有机骨架和沸石作为有机反应的非均相催化剂的异同

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摘要

This perspective article is aimed at providing a comparison of similarities and dissimilarities between the catalytic properties of zeolites and metal organic frameworks (MOFs). In the first part of the paper, we comment the general characteristics of MOFs with relevance to catalysis, making emphasis of how the properties of MOFs can serve to compliment those of zeolites as catalysts. The lower chemical and thermal stability of MOFs compared to zeolites is commented and correlated to the requirements for some liquid-phase reactions conducted under mild conditions. In the second part, we discuss the behaviour of zeolites and MOFs for four types of general organic reactions (acid catalysed, base catalysed, oxidation and hydrogenations). Particular attention is paid to provide critical comments on how MOFs could be adapted by design or can be modified by post-synthetic treatments to give well performing catalysts.
机译：该观点文章旨在比较沸石和金属有机骨架（MOF）的催化性能之间的相似性和不相似性。在本文的第一部分中，我们评论了与催化作用有关的MOF的一般特征，着重强调了MOF的性质如何可以与沸石作为催化剂的性质相辅相成。评论了MOF与沸石相比较低的化学和热稳定性，并且与在温和条件下进行的某些液相反应的要求相关。在第二部分中，我们讨论了四种类型的一般有机反应（酸催化，碱催化，氧化和氢化）中沸石和MOF的行为。尤其要注意就MOF如何通过设计进行适应或如何通过合成后处理进行修饰以提供性能良好的催化剂提供批评意见。

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