Bridging, terminal, free, anti and gauche BPA ligands in a 1D hybrid organic-inorganic Mn~(II)-cyanate system

De La Pinta N.; Fidalgo L.; Madariaga G.; Mautner F.A.; Lezama L.; Cortés R.

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Bridging, terminal, free, anti and gauche BPA ligands in a 1D hybrid organic-inorganic Mn~(II)-cyanate system

机译：一维杂化有机-无机Mn〜（II）-氰酸酯体系中的桥联，末端，游离，反和Gauche BPA配体

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A hybrid organic-inorganic chain compound of the family Mn(ii)-bpa-(NCO) is presented. It contains, unusually, five different dispositions for the bpa [1,2-bis(4-pyridyl)ethane] ligand. Water molecules and free bpa ligands occupy the voids of the structure. The compound shows significant antiferromagnetic- type interactions as a consequence of different exchange pathways.

机译：提出了Mn（ii）-bpa-（NCO）家族的杂化有机-无机链化合物。不寻常地，它包含bpa [1,2-双（4-吡啶基）乙烷]配体的五个不同位置。水分子和游离的bpa配体占据了结构的空隙。由于不同的交换途径，该化合物显示出明显的反铁磁型相互作用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第22期|共5页
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De La Pinta N.; Fidalgo L.; Madariaga G.; Mautner F.A.; Lezama L.; Cortés R.;
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1. Bridging, terminal, free, anti and gauche BPA ligands in a 1D hybrid organic-inorganic Mn~(II)-cyanate system [J] . De La Pinta N., Fidalgo L., Madariaga G., Dalton transactions: An international journal of inorganic chemistry . 2011,第22期

机译：一维杂化有机-无机Mn〜（II）-氰酸酯体系中的桥联，末端，游离，反和Gauche BPA配体
2. Synthesis, X-ray structure, polarized optical spectra and DFT theoretical calculations of two new organic-inorganic hybrid fluoromanganates(III): (bpaH_2)[MnF_4(H_2O)_2]_2 and (bpeH_2)[MnF_4(H_2O)_2]_2 [J] . Pedro Nunez, Juan C. Ruiz-Morales, A. D. Lozano-Gorrin, Dalton transactions: An international journal of inorganic chemistry . 2004,第2期

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5. I. Proton transfer to terminal and bridging oxo ligands. II. Iron binding to the apoprotein of horse spleen ferritin. [D] . Kumar, Divya. 2006

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7. Organic–inorganic Mn(II)-cyanate compound with five dispositions of bpa ligand [O] . R. Cortés, N. De la Pinta, G. Madariaga, 2011

机译：有机 - 无机Mn（II） - 氰酸酯化合物，具有BPA配体的五个配置

Bridging, terminal, free, anti and gauche BPA ligands in a 1D hybrid organic-inorganic Mn~(II)-cyanate system

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