The nature of the chlorination reaction in [1-C_6H _5-1-CB_9H_9]~- boron clusters

Farràs P.; Vi?as C.; Sillanp?? R.; Teixidor F.; Rey M.

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The nature of the chlorination reaction in [1-C_6H _5-1-CB_9H_9]~- boron clusters

机译：[1-C_6H _5-1-CB_9H_9]〜-硼团簇中氯化反应的性质

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Preferential chlorination sites resulting from sequential radical substitution reactions in carborane anions have been studied combining experimental and computational methods. Results have been obtained experimentally by mixing the substrate with incremental ratios of N-chlorosuccinimide and analysing the resulting samples by negative MALDI-TOF-MS. The theoretical results have been obtained calculating the 2a-NPA charges on the starting material and computing the most energetically favourable reaction pathway.

机译：结合实验和计算方法研究了碳硼烷阴离子中顺序自由基取代反应产生的优选氯化位点。通过将底物与递增比例的N-氯代琥珀酰亚胺混合并通过阴性MALDI-TOF-MS分析所得样品，可以通过实验获得结果。已经获得了理论结果，计算了起始材料上的2a-NPA电荷并计算了最有利于能量的反应途径。

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《Dalton transactions: An international journal of inorganic chemistry》 |2010年第33期|共8页
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Farràs P.; Vi?as C.; Sillanp?? R.; Teixidor F.; Rey M.;
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1. The nature of the chlorination reaction in [1-C_6H _5-1-CB_9H_9]~- boron clusters [J] . Farràs P., Vi?as C., Sillanp?? R., Dalton transactions: An international journal of inorganic chemistry . 2010,第33期

机译：[1-C_6H _5-1-CB_9H_9]〜-硼团簇中氯化反应的性质
2. Borane reaction chemistry. Alkyne insertion reactions into boron-containing clusters. Products from the thermolysis of [6,9-(2-HC C-C5H4N)(2)-arachno-B10H12] [J] . Bould J, Laromaine A, Bullen NJ, Dalton transactions: An international journal of inorganic chemistry . 2008,第12期

机译：硼烷反应化学。炔烃插入反应进入含硼簇中。 [6,9-（2-HC C-C5H4N）（2）-芳族-B10H12]的热解产物
3. Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotron X-ray structures of [(eta(5)-C5Me5)(2)Ir2B16H17Cl] and [(eta(5)-C5Me5)(2)Ir2B16H15Cl [J] . Carr MJ, Perera SD, Jelinek T, Dalton transactions: An international journal of inorganic chemistry . 2006,第44期

机译：宏观多面体含硼簇化学。 B16H20与[{（IrCl2（eta（5）-C5Me5）}（2）]反应中的簇开放和B架重排。[（eta（5）-C5Me5）（2）Ir2B16H17Cl的同步X射线结构]和[（eta（5）-C5Me5）（2）Ir2B16H15Cl
4. Carbonaceous materials mediate redox reactions of chlorinated hydrocarbons in aqueous solution: environmental implications [C] . Yao Li, Weifeng Chen, Dongqiang Zhu, Proceedings of 2013 international symposium on environmental science and technology . 2013

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5. Part I. Layered double hydroxides (LDHs): Organic anion exchange reactions, synthesis of microporous pillared derivatives and surface chemistry of metal carbonyl clusters. Part II. On the nature of titania pillared layered silicate clays. [D] . Dimotakis, Emmanuel Dimitrios. 1991

机译：第一部分：层状双氢氧化物（LDHs）：有机阴离子交换反应，微孔柱状衍生物的合成和羰基金属簇的表面化学。第二部分在二氧化钛的性质上有柱状层状硅酸盐粘土。
6. Sequence analysis of the Pseudomonas sp. strain P51 tcb gene cluster which encodes metabolism of chlorinated catechols: evidence for specialization of catechol 12-dioxygenases for chlorinated substrates. [O] . J R van der Meer, R I Eggen, A J Zehnder, 1991

机译：假单胞菌菌种的序列分析。菌株P51 tcb基因簇其编码氯化邻苯二酚的代谢：专门用于氯化底物的邻苯二酚12-二加氧酶的证据。
7. First-principles calculation of the electronic properties of graphene clusters doped with nitrogen and boron: Analysis of catalytic activity for the oxygen reduction reaction [O] . Huang, Sheng-Feng, Terakura, Kiyoyuki, Ozaki, Taisuke, 2009

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The nature of the chlorination reaction in [1-C_6H _5-1-CB_9H_9]~- boron clusters

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