Tetrapodal amidoxime ligands I. Coordination isomerism due to self-complementary dimerization of a pyramidal cobalt(iii) coordination module

Boyd J.P.; Irran E.; Grohmann A.

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Tetrapodal amidoxime ligands I. Coordination isomerism due to self-complementary dimerization of a pyramidal cobalt(iii) coordination module

机译：四足型a胺肟配体I.金字塔形钴（iii）配位模块自互补二聚化导致的配位异构

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A bis-μ-amidoximato-bridged cobalt(iii) dimer obtained with a new tetrapodal ligand possesses interesting structural parameters as a consequence of intramolecular hydrogen bonding intentionally built into the complex. Its synthesis and properties are described. The new ligand type combines attributes of two previously described ligand classes: It binds a metal ion in a tetrapodal pentadentate fashion and forms a pseudomacrocycle through hydrogen bonds, characteristic of chelating oxime ligands. Coordination isomerism, which is a consequence of dimer formation, has been analyzed by means of X-ray crystallography and carbon-13 nuclear magnetic resonance spectroscopy.

机译：通过新的四足配体获得的双-μ-酰胺基桥接的钴（iii）二聚体具有有趣的结构参数，这是由于分子内氢键故意内置在配合物中。描述了其合成和性质。新的配体类型结合了先前描述的两种配体类型的属性：它以四足五极体的形式结合金属离子，并通过氢键形成螯合肟配体的特征的假大环。由于二聚体形成的结果，配位异构现象已经通过X射线晶体学和碳13核磁共振光谱法进行了分析。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第8期|共9页
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Boyd J.P.; Irran E.; Grohmann A.;
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1. Tetrapodal amidoxime ligands I. Coordination isomerism due to self-complementary dimerization of a pyramidal cobalt(iii) coordination module [J] . Boyd J.P., Irran E., Grohmann A. Dalton transactions: An international journal of inorganic chemistry . 2012,第8期

机译：四足型a胺肟配体I.金字塔形钴（iii）配位模块自互补二聚化导致的配位异构
2. "Embroidered"Square Pyramidal Coordination Caps for Nickel(II):Mono-,Di-and Tetrafunctionalisation of a Tetrapodal Pentadentate Ligand with an NN_4 Donor Set [J] . Dietz Christian European journal of inorganic chemistry . 1999,第12期

机译：镍（II）的“绣花”方形金字塔形配位帽：具有NN_4供体集的四足五齿配体的单官能，双官能和四官能化
3. Old ligands with new coordination chemistry:Linear trinuclear mixed oxidation state cobalt(III/II/III) complexes and their mononuclear "ligand" cobalt(III) complexes featuring 2-pyridyloximates [J] . Theocharis C.Stamatatos, Spyros P.Perlepes, Richard E.P.Winpenny, Inorganic Chemistry Communications . 2005,第6期

机译：具有新配位化学的旧配体：线性三核混合氧化态钴（III / II / III）配合物及其具有2-吡啶基肟酸的单核“配体”钴（III）配合物
4. Study on the Coordination of Amidoxime Small Molecule Ligands with Uranyl Ions Under Seawater Conditions [C] . Tingting Liu, Suliang Yang, Qian Liu, International Nuclear Fuel Cycle Conference . 2019

机译：海水条件下亚烷离子与亚烷离子的配位研究
5. Part A: Coordination of pyridine and pyridine-type ligands to cobalt(II)- and cobalt(III)-substituted Keggin and Dawson-type heteropolyanions. Part B: Encapsulation of various heteropolyanions in artificial phospholipid vesicles: Effects of size, charge, and polarity on encapsulation efficiency. [D] . Samonte, Joseph Laurito. 1996

机译：A部分：吡啶和吡啶型配体与钴（II）和钴（III）取代的Keggin和Dawson型杂多阴离子的配位。 B部分：在人工磷脂囊泡中包裹各种杂多阴离子：大小，电荷和极性对包裹效率的影响。
6. Synthesis and Characterization of trans-Dichlorotetrakis(imidazole)cobalt(III) Chloride: A New Cobalt(III) Coordination Complex with Potential Prodrug Properties [O] . Kaila F. Hart, Natalie S. Joe, Rebecca M. Miller, 2018

机译：反式二氯四咪唑钴（III）的合成和表征：具有潜在前药性质的新型钴（III）配合物
7. Tetrapodal amidoxime ligands I. Coordination isomerism due to self-complementary dimerization of a pyramidal cobalt(III) coordination module [O] . Boyd John P., Irran Elisabeth, Grohmann Andreas 2012

机译：四足型a胺肟配体I.金字塔形钴（III）配位模块自互补二聚化导致的配位异构
8. Spectrophotometric Determination of Cobalt(II) In the Presence of the Cobalt(III) Coordination Compound 2-(5-Cyanotetrazolato)Pentaamminecobalt(III) Perchlorate [R] . Merrill, R. M. 1980

机译：钴（III）配位化合物2-（5-氰基四唑）五氮杂钴（III）高氯酸盐存在下分光光度法测定钴（Ⅱ）

Tetrapodal amidoxime ligands I. Coordination isomerism due to self-complementary dimerization of a pyramidal cobalt(iii) coordination module

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