A rectangular Ni-Fe cluster with unusual cyanide bridges

Christoph Krüger; Hiroki Sato; Takuto Matsumoto; Takuya Shiga; Graham N. Newton; Franz Renz; Hiroki Oshio

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A rectangular Ni-Fe cluster with unusual cyanide bridges

机译：具有不寻常的氰化物桥的矩形Ni-Fe团簇

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An asymmetric polycyanide iron complex, K_2[Fe~(III)(Ll)-(CN)_4](MeOH) (HL1 = 2,2'-(lH-pyrazole-3,5-diyl)bis-pyri-dine), was synthesized and its complexation compatibility with nickel ions was examined. Two kinds of enantiomeric nickel-iron squares were obtained in the presence of a chiral bidentate capping ligand. The compounds display unusual cyanide bridge geometry and have ferromagnetic interactions between nickel and iron ions.

机译：一种不对称的多氰化物铁络合物K_2 [Fe〜（III）（Ll）-（CN）_4]（MeOH）（HL1 = 2,2'-（1H-吡唑-3,5-二基）双-吡啶二胺）合成了，并研究了其与镍离子的络合相容性。在手性双齿封端配体的存在下获得两种对映体镍-铁正方形。这些化合物显示出不同寻常的氰化物桥几何结构，并且在镍和铁离子之间具有铁磁相互作用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第37期|共3页
作者
Christoph Krüger; Hiroki Sato; Takuto Matsumoto; Takuya Shiga; Graham N. Newton; Franz Renz; Hiroki Oshio;
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中图分类化学;
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1. A rectangular Ni-Fe cluster with unusual cyanide bridges [J] . Christoph Krüger, Hiroki Sato, Takuto Matsumoto, Dalton transactions: An international journal of inorganic chemistry . 2012,第37期

机译：具有不寻常的氰化物桥的矩形Ni-Fe团簇
2. Unusual Reactions of Cationic Bridging Carbyne Complexes of Dimethylsilane-Bridged Bis(#eta#~5-cyclopentadienyl)diiron Tricarbonyl with Nucleophiles. A Route to Iron-Sulfur Cluster Bridging Carbene Complexes [J] . Ruitao Wang, Qiang Xu, Li-Cheng Song Organometallics . 2001,第19期

机译：二甲基硅烷桥联的双（＃eta＃〜5-环戊二烯基）二铁三羰基阳离子桥联卡宾络合物与亲核试剂的异常反应。通往铁硫簇桥联碳络合物的途径
3. Formation and structural chemistry of the unusual cyanide-bridged dinuclear species [Ru2(NN)2(CN)7]3 (NN = 2,20-bipyridine or 1,10-phenanthroline) [J] . Sofia Derossi, Svetlana G. Baca, Thomas A. Miller, Inorganica Chimica Acta . 2009,第4期

机译：罕见的氰化物桥联双核物种[Ru2（NN）2（CN）7] 3（NN = 2,20-联吡啶或1,10-菲咯啉）的形成和结构化学
4. Spin Crossover in Cyanide-Bridged {Fe~(III)_2Fe~(II)_2} Tetranuclear Cluster with Chiral Ligand [C] . Junqiu Li, Kanegawa Shinji, Osamu Sato 日本化学会春季年会講演予稿集 . 2018

机译：氰化物桥接{Fe〜（III）_2FE〜（II）_2}与手性配体的四核簇旋转交叉
5. Preparation and characterization of cyanide-bridged molecular clusters and extended networks using the building-block approach. [D] . Karadas, Ferdi. 2009

机译：使用结构单元方法制备和表征氰化物桥接的分子簇和扩展网络。
6. Various Structural Types of Cyanide-Bridged FeIII–MnIII Bimetallic Coordination Polymers (CPs) and Polynuclear Clusters Based-on A New mer-Tricyanoiron(III)Building Block: Synthesis Crystal Structures and Magnetic Properties [O] . Wenlong Lan, Xiaoyun Hao, Yong Dou, 2019

机译：基于新的三氰基铁（III）构建基的氰化桥联的FeIII-MnIII双金属配位聚合物（CP）和多核簇的各种结构类型：合成晶体结构和磁性
7. A rectangular Ni-Fe cluster with unusual cyanide bridges [O] . Krüger C., Sato H., Matsumoto T., 2012

机译：具有不寻常的氰化物桥的矩形Ni-Fe团簇
8. Oxidation State Properties of Delocalized, Ligand-Bridged Metal Complexes. (Ru3O(CH3CO2)6L3)n+ and the Pyrazine-Bridged, Cluster-Cluster Dimer, (Ru3O(CH3CO2)6(py)2)2pyzm+. [R] . Wilson, S. T., Bondurant, R. F., Meyer, T. J., 1975

机译：离域，配体桥联金属配合物的氧化态特性。（Ru 3 O（CH 3 CO 2）6 L 3）n +和吡嗪桥联，簇 - 簇二聚体，（Ru 3 O（CH 3 CO 2）6（py）2）2pyzm +。

A rectangular Ni-Fe cluster with unusual cyanide bridges

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