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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Coordination polymer incorporating maleonitriledithiolate copper clusters: electrocrystallization synthesis and crystal structure of (NPr4)(2)[Cu(MeCN)](2)[Cu-8(i-mnt)(6)]center dot(MeCN)(0.5)center dot(THF)(0.25)
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Coordination polymer incorporating maleonitriledithiolate copper clusters: electrocrystallization synthesis and crystal structure of (NPr4)(2)[Cu(MeCN)](2)[Cu-8(i-mnt)(6)]center dot(MeCN)(0.5)center dot(THF)(0.25)

机译:包含马来腈三硫代铜盐簇的配位聚合物:(NPr4)(2)[Cu(MeCN)](2)[Cu-8(i-mnt)(6)]中心点(MeCN)(0.5)中心的电结晶合成和晶体结构点(THF)(0.25)

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摘要

(NPr4)(2)[Cu-I(MeCN)](2)[Cu-I (8)(i-mnt)(6)].(MeCN)(0.5).(THF)(0.25) is prepared by electrocrystallization of a solution of (NPr4)(4)[Cu-I (8)(i-mnt)(6)]; the crystal structure consists in bidimensional layers characterised by coordination of copper atoms by the cyano groups of the iso-maleonitriledithiolate ligand of the octa-copper cluster.
机译:(NPr4)(2)[Cu-I(MeCN)](2)[Cu-I(8)(i-mnt)(6)]。(MeCN)(0.5)。(THF)(0.25)的制备如下(NPr4)(4)[Cu-I(8)(i-mnt)(6)]溶液的电结晶;晶体结构由二维层组成,其特征在于铜原子被八-铜簇的异马来三硫代硫酸盐配体的氰基配位。

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