Hydroalumination reactions on acetylenes and nitriles in the synthesis of carbaalanes and imidoalanes: an overview

Kumar SS; Roesky HW

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Hydroalumination reactions on acetylenes and nitriles in the synthesis of carbaalanes and imidoalanes: an overview

机译：氨基甲酸酯和亚氨基丙酸酯合成中乙炔和腈的水铝化反应概述

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Hydroalumination reactions play an important role in industry as well as from the point of view of academics. The area of carbaalane chemistry is in its infant stage whereas aluminium nitride chemistry has generated a lot of interest from the synthetic and material science perspective. In this overview, we address the simple way of carrying out the hydroalumination reactions on acetylenes and nitriles in the synthesis of carbaalane and imidoalane cluster compounds. A possible mechanism involved in the synthesis of these compounds is discussed. Heteronuclear carbaalane and imidoalane clusters containing transition metals have also been emphasized.

机译：从学者的角度来看，水铝化反应在工业中起着重要作用。碳硼烷化学领域还处于起步阶段，而氮化铝化学从合成和材料科学的角度引起了很多兴趣。在本概述中，我们介绍了在合成碳烷烃和亚胺基烷烃簇化合物时，对乙炔和腈进行加氢铝化反应的简单方法。讨论了这些化合物的合成中可能的机制。还强调了含有过渡金属的异核碳烷烃和亚胺基烷烃簇。

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《Dalton transactions: An international journal of inorganic chemistry》 |2004年第23期|共11页
作者
Kumar SS; Roesky HW;
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正文语种 eng
中图分类无机化学;
关键词
GROUP-III NITRIDES; MOLECULAR-STRUCTURE; STRUCTURAL-CHARACTERIZATION; ORGANOALUMINUM COMPOUNDS; CRYSTAL-STRUCTURE; ALUMINUM IMIDE; PRIMARY AMINES; CHEMISTRY; STEREOCHEMISTRY; POLY(N-ALKYLIMINOALANES);

机译：Ⅲ族氮化物;分子结构;结构特征;有机铝化合物;晶体结构;铝酰亚胺;主胺;化学;立体化学;聚（N-烷基亚氨基）芳烃;

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1. Hydroalumination reactions on acetylenes and nitriles in the synthesis of carbaalanes and imidoalanes: an overview [J] . Kumar SS, Roesky HW Dalton transactions: An international journal of inorganic chemistry . 2004,第23期

机译：氨基甲酸酯和亚氨基丙酸酯合成中乙炔和腈的水铝化反应概述
2. Reactions of aminobenzoic acids with alpha,beta-acetylenic gamma-hydroxy nitriles: synthesis of functionalized amino acids and unusually facile esterification and acetylene hydration [J] . Trofimov BA, Malkina AG, Shemyakina OA, Tetrahedron . 2009,第12期

机译：氨基苯甲酸与α，β-炔属γ-羟基腈的反应：官能化氨基酸的合成以及异常容易的酯化和乙炔水合
3. One-pot synthesis of 2,3,5-substituted 1H-pyrroles via the reaction of terminal acetylenes with nitriles and EtAlCl2 catalyzed by Cp2TiCl2 [J] . Khafizova Leila O., Shaibakova Mariya G., Rikhter Nikita A., Tetrahedron . 2019,第7期

机译：通过CP2TICL2催化的甲基乙烯基末端的反应合成2,3,5-取代的1H-辐注1H-辐注1H-辐注1小时
4. Synthesis of Lactones and Lactams via Sequential trans-Hydroalumination/Carboxylation/Condensation Reactions ofPropargyl Alcohols and Amines [C] . WenlongCHEN, Woo-JinYOO, ShuKOBAYASHI 日本化学会春季年会 . 2020

机译：通过顺序反式氢透射液/羧化/缩合反应的顺序反式羟氢盐和羟基醇和胺合成乳酰胺和内酰胺
5. Synthesis and characterization of new nitrile-containing acetylenic monomers and polymers. [D] . Densmore, Crystal G. 2003

机译：新型含腈乙炔单体和聚合物的合成与表征。
6. Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer [O] . Yunosuke Abe, Toshiki Aoki, Hongge Jia, 2012

机译：通过膜态的两步聚合反应合成稳定且可溶的单手螺旋均聚（取代的乙炔）而无其他手性部分的合成：起始单体的分子设计
7. Hydroalumination of silylacetylenes: a novel and highly stereoselective synthesis of (E)-telluro(silyl)ketene acetals and their applications in Sonogashira cross-coupling reactions [O] . Kawasoko Cristiane Y., Nazario Carlos E.D., Santana Amanda S., 2011

机译：甲硅烷基乙炔的氢铝化：（E）-碲（甲硅烷基）酮缩醛的新型且高度立体选择性的合成及其在Sonogashira交叉偶联反应中的应用
8. Transfer Pd(0) Catalyzed Polymerization Reactions. 5. Synthesis and ThermalCharacterization of 1,2-(4,4'-di(S(-)-2-methylbutyloxy)phenyl) acetylene and 1-(4-n-alkoxyphenyl)-2-(4'-(S(-)-2-methylbutyloxy)phenyl)acetylene Monomers [R] . Pugh, C., Tarnstrom, C., Percec, V. 1991

机译：转移pd（0）催化的聚合反应。 5. 1,2-（4,4'-二（s（ - ） - 2-甲基丁氧基）苯基）乙炔和1-（4-正烷氧基苯基）-2-（4' - （s（s）的合成和热表征 - ） - 2-甲基丁氧基）苯基）乙炔单体

Hydroalumination reactions on acetylenes and nitriles in the synthesis of carbaalanes and imidoalanes: an overview

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