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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Open,cyclic,and bicyclic compounds of double silylated phosphorus and boron
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Open,cyclic,and bicyclic compounds of double silylated phosphorus and boron

机译:硅烷化的磷和硼双开环,双环和双环化合物

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摘要

Salt elimination reactions of tris(trimethylsilyl)silyl potassium(1),and two 1,4-dipotassiooligosilanes(3,5)with 2,2,6,6-tetramethylpiperidinodichloroborane and diethylaminodichlorophosphane have generated open(2),cyclic(4)and bicyclic(6)bora-and phosphaoligosilanes.A monosilylated phosphane and the two five-membered cyclosilanes have been subjected to single crystal X-ray diffraction analysis.
机译:三(三甲基甲硅烷基)甲硅烷基钾(1)和两种1,4,2-二苯并低聚硅烷(3,5)与2,2,6,6-四甲基哌啶二氯硼烷和二乙氨基二氯膦的盐消除反应产生了开环(2),环(4)和双硅烷基化的膦和两个五元环硅烷已经过单晶X射线衍射分析。

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