Ruthenium amino carboxylate complexes as asymmetric hydrogen transfer catalysts

Carmona D.; Viguri F.; Pilar Lamata M.; Ferrer J.; Bardají E.; Lahoz F.J.; García-Ordu?a P.; Oro L.A.

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Ruthenium amino carboxylate complexes as asymmetric hydrogen transfer catalysts

机译：氨基钌羧酸络合物作为不对称氢转移催化剂

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The synthesis and characterization of optically active amino carboxylate complexes of formula [(η ~6-arene)Ru(Aa)Cl] (arene = C _6H _6, C _6Me _6, Aa = amino carboxylate) as well as those of the related trimers [{(η ~6-arene)Ru(Aa)} _3][BF _4] _3 are reported. Trimerization takes place with chiral self-recognition: only diastereomers equally configured at the metal, R _(Ru)R _(Ru)R _(Ru) or S _(Ru)S _(Ru)S _(Ru), are detected. The crystal structures of the complexes [(η ~6-C _6H _6)Ru(Pip)Cl] and [{(η ~6-C _6Me _6)Ru(Pro)} _3][BF _4] _3 have been determined by X-ray diffraction methods. Both types of complexes catalyse the hydrogen transfer reaction from 2-propanol to ketones with moderate enantioselectivity (up to 68% ee). The enantiodifferentiation achieved can be accounted for by assuming that Noyori's bifunctional mechanism is operating.

机译：式[（η〜6-芳烃）Ru（Aa）Cl]（芳烃= C _6H _6，C _6Me _6，Aa =氨基羧酸盐）以及相关三聚体的旋光活性氨基羧酸盐配合物的合成与表征报告了[{（η〜6-芳烃基Ru（Aa）} _3] [BF _4] _3。三聚反应是通过手性自我识别进行的：只有在金属R_（Ru）R_（Ru）R_（Ru）或S_（Ru）S_（Ru）S_（Ru）上均等配置的非对映异构体检测到。配合物[（η〜6-C _6H _6）Ru（Pip）Cl]和[{（η〜6-C _6Me _6Me _6Me _6）Ru（Pro）} _3] [BF _4] _3的晶体结构已确定X射线衍射法。两种类型的络合物均以中等对映选择性（最高ee为68％）催化从2-丙醇到酮的氢转移反应。可以通过假设Noyori的双功能机制起作用来解释实现的对映分化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第34期|共11页
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Carmona D.; Viguri F.; Pilar Lamata M.; Ferrer J.; Bardají E.; Lahoz F.J.; García-Ordu?a P.; Oro L.A.;
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1. Ruthenium amino carboxylate complexes as asymmetric hydrogen transfer catalysts [J] . Carmona D., Viguri F., Pilar Lamata M., Dalton transactions: An international journal of inorganic chemistry . 2012,第34期

机译：氨基钌羧酸络合物作为不对称氢转移催化剂
2. Synthesis and electrochemical characterization of iminophosphine-based ruthenium(II) complexes and application in asymmetric transfer hydrogenation reaction as catalysts [J] . Keles Mustafa, Keles Hulya, Yilmaz Mustafa Kemal Journal of the Iranian Chemical Society . 2019,第5期

机译：基于硫代磷酸钌（II）复合物的合成与电化学表征及在不对称转移氢化反应中的应用作为催化剂
3. Half-sandwich ruthenium(II) and rhodium(III) complexes bearing chiral amino-phosphoramidite ligands: Synthesis, characterization and application in asymmetric transfer hydrogenation of acetophenone [J] . Arena C.G., Cuzzola A., Drommi D. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2012,第Null期

机译：带有手性氨基-亚磷酰胺配体的半三明治钌（II）和铑（III）配合物：苯乙酮的不对称转移氢化反应的合成，表征和应用
4. Effective Asymmetric Transfer Hydrogenation of Ketones Catalyzed by A New Chiral P-N-P Ligand-Ruthenium Complexes [C] . Yoji Oderaotoshi, Yuki Noguchi, Satoshi Minakata Symposium on Organometallic Chemistry . 2006

机译：新的手性P-N-P配体 - 钌配合物催化的酮催化的有效不对称转移氢化
5. Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of aromatic ketones using new ferrocene-based amino-phosphine ligands featuring planar chirality [D] . Vue, Bao 2008

机译：使用具有平面手性的新型二茂铁基氨基膦配体，钌（II）催化芳族酮的不对称转移氢化
6. Asymmetric Transfer Hydrogenation of Arylketones Catalyzed by Enantiopure Ruthenium(II)/Pybox Complexes Containing Achiral Phosphonite and Phosphinite Ligands [O] . Miguel Claros, Eire de Julián, Josefina Díez, 2020

机译：含有手性亚膦酸酯和次膦酸酯配体的对映纯钌（II）/ Pybox配合物催化芳基酮的不对称转移加氢
7. Ruthenium amino carboxylate complexes as asymmetric hydrogen transfer catalysts [O] . Carmona Daniel, Viguri Fernando, Lamata M. Pilar, 2013

机译：氨基钌羧酸络合物作为不对称氢转移催化剂

Ruthenium amino carboxylate complexes as asymmetric hydrogen transfer catalysts

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