First crystallographic elucidation of a high-valent molybdenum oxo N-heterocyclic carbene complex [CpMo ~(VI)O _2(IBz)] _2[Mo _6O _(19)]

Li S.; Wang Z.; Hor T.S.A.; Zhao J.

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First crystallographic elucidation of a high-valent molybdenum oxo N-heterocyclic carbene complex [CpMo ~(VI)O _2(IBz)] _2[Mo _6O _(19)]

机译：高价钼羰基N-杂环卡宾络合物[CpMo〜（VI）O _2（IBz）] _2 [Mo _6O _（19）]的首次晶体学阐明

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A high-valent molybdenum NHC dioxo complex [CpMoO _2(IBz)] _2[Mo _6O _(19)] (IBz = 1,3-dibenzylimidazol-2- ylidene) has been isolated in its hexamolybdate form and crystallographically elucidated to show a Mo-C(NHC) bond of 2.173(4) ?. (NHC = N-heterocyclic carbene).

机译：已分离出六价钼酸盐形式的高价NHC二氧钼钼络合物[CpMoO _2（IBz）] _2 [Mo -6O _（19）]（IBz = 1,3-二苄基咪唑-2-亚烷基），并通过结晶学分析显示出2.173（4）Ω的Mo-C（NHC）键。（NHC ＝ N-杂环卡宾）。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第5期|共3页
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Li S.; Wang Z.; Hor T.S.A.; Zhao J.;
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1. First crystallographic elucidation of a high-valent molybdenum oxo N-heterocyclic carbene complex [CpMo ~(VI)O _2(IBz)] _2[Mo _6O _(19)] [J] . Li S., Wang Z., Hor T.S.A., Dalton transactions: An international journal of inorganic chemistry . 2012,第5期

机译：高价钼羰基N-杂环卡宾络合物[CpMo〜（VI）O _2（IBz）] _2 [Mo _6O _（19）]的首次晶体学阐明
2. Molybdenum imido alkylidene and tungsten oxo alkylidene N-heterocyclic carbene complexes for olefin metathesis [J] . Sen Suman, Schowner Roman, Buchmeiser Michael R. Monatshefte fur Chemie . 2015,第7期

机译：钼亚胺基亚烷基和氧代亚烷基钨的N-杂环卡宾配合物用于烯烃复分解
3. Molybdenum imido alkylidene and tungsten oxo alkylidene N-heterocyclic carbene complexes for olefin metathesis [J] . Suman Sen, Roman Schowner, Michael R. Buchmeiser Monatshefte für Chemie - Chemical Monthly . 2015,第7期

机译：酰亚胺亚钼亚烷基钼和氧代亚烷基钨N-杂环卡宾配合物用于烯烃复分解
4. Controlled Radical Polymerization of Vinyl Monomers Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes [C] . Sebastien Delfosse, Aurore Richel, Lionel Delaude, American Chemical Society . 2006

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5. Novel N-heterocyclic dicarbene ligands and molybdenum and dimolybdenum N-heterocyclic carbene complexes [D] . Bemowski, Ross David 2013

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6. A combined magnetic circular dichroism and density functional theory approach for the elucidation of electronic structure and bonding in three- and four-coordinate iron(ii)–N-heterocyclic carbene complexes [O] . Kathlyn L. Fillman, Jacob A. Przyojski, Malik H. Al-Afyouni, 2015

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7. Reactivity of Cyclopentadienyl Molybdenum Compounds towards Formic Acid: Structural Characterization of CpMo(PMe3)(CO)2H, CpMo(PMe3)2(CO)H, CpMo(-O)(O2CH)2, and Cp*Mo(-O)(O2CH)2 [O] . -1

机译：环戊二烯基钼化合物对甲酸的反应性：CPMO（PME3）（CO）2H，CPMO（PME3）2（CO）H，CPMO（-O）（O2CH） 2，CP * MO（ - O）（O2CH） 2
8. Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene-Isoquinoline Complex. [R] . Sara, V., Kornenko, N., Margarit, C. G., 2013

机译：可见光光催化氧化催化：用镍N-杂环卡宾 - 异喹啉配合物选择性还原二氧化碳为一氧化碳。

First crystallographic elucidation of a high-valent molybdenum oxo N-heterocyclic carbene complex [CpMo ~(VI)O _2(IBz)] _2[Mo _6O _(19)]

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