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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Layered hybrid organic-inorganic nanobelts: Synthesis and removal of trace heavy metal ions
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Layered hybrid organic-inorganic nanobelts: Synthesis and removal of trace heavy metal ions

机译:层状杂化有机-无机纳米带:合成和去除痕量重金属离子

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Cobalt phosphate-based organic-inorganic hybrid nanobelts were successfully synthesized in the presence of trioctylamine (TOA) via a solvothermal system. The inorganic cobalt phosphate layers and organic n-octylamine layers in this structure arranged alternately, both of which were parallel to the axial direction of the nanobelts, and the layered distance is 4.0 nm. The formation of this nanostructure proceeds via two reactions. Trioctylamine molecules undergo C-N bond cleavage to form octylamine via the redox reaction between the Co(iii) and trioctylamine. Octylamine was protonated to incorporate into the inorganic framework, resulting in the formation of organic-inorganic hybrid nanobelts. In addition, the as-synthesized nanobelts show excellent removal ability for the trace heavy metal ion Pb ~(2+) in wastewater.
机译:在三辛胺(TOA)存在下,通过溶剂热系统成功地合成了磷酸钴基有机-无机杂化纳米带。该结构中的无机磷酸钴层和有机正辛胺层交替排列,两者均与纳米带的轴向平行,层间距离为4.0nm。该纳米结构的形成通过两个反应进行。三辛胺分子通过Co(iii)与三辛胺之间的氧化还原反应经历C-N键裂解形成辛胺。辛胺质子化并结合到无机骨架中,从而形成有机-无机杂化纳米带。此外,合成后的纳米带对废水中的痕量重金属离子Pb〜(2+)具有优异的去除能力。

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