Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

Romain C.; Rosa V.; Fliedel C.; Bier F.; Hild F.; Welter R.; Dagorne S.; Avilés T.

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Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

机译：高活性的烷基锌阳离子，用于ε-己内酯的可控和永生开环聚合

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Zinc alkyl cations supported by N,N-BIAN-type bidentate ligands were found to be highly active in the immortal ROP of ε-caprolactone to yield narrowly disperse and chain length-controlled poly(ε-caprolactone), whether in solution or bulk polymerization conditions.

机译：发现N，N-BIAN型双齿配体负载的烷基锌阳离子在ε-己内酯的不朽ROP中具有很高的活性，无论是在溶液聚合还是本体聚合中，都能产生窄分散和链长受控的聚（ε-己内酯）条件。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第12期|共3页
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Romain C.; Rosa V.; Fliedel C.; Bier F.; Hild F.; Welter R.; Dagorne S.; Avilés T.;
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正文语种 eng
中图分类化学;
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1. Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone [J] . Romain C., Rosa V., Fliedel C., Dalton transactions: An international journal of inorganic chemistry . 2012,第12期

机译：高活性的烷基锌阳离子，用于ε-己内酯的可控和永生开环聚合
2. Metal Triflates as Highly Stable and Active Catalysts for the "Immortal" Ring-Opening Polymerization of Trimethylene Carbonate [J] . Marion Helou, Olivier Miserque, Jean-Michel Brusson ChemCatChem . 2010,第3期

机译：金属三氟甲磺酸酯是碳酸三亚甲基酯“非凡”开环聚合的高度稳定和活性催化剂
3. Highly Active Yttrium Catalysts for the Ring-Opening Polymerization of epsilon-Caprolactone and delta-Valerolactone [J] . Wang Xinke, Brosmer Jonathan L., Thevenon Arnaud, Organometallics . 2015,第19期

机译：ε-己内酯和δ-戊内酯开环聚合的高活性钇催化剂
4. Temperature control of a highly active catalyst polyolefin polymerization reactor at an unstable operating point [C] . M. Ogawa, S. Ohyama, F. Watanabe, IFAC symposium on dynamics and control of process systems;DYCOPS-5 . 1999

机译：高活性催化剂聚烯烃聚合反应器在不稳定工作点的温度控制
5. New high-activity zinc(II)-based catalysts for ring-opening polymerization: Synthesis of stereoregular biodegradable polymers. [D] . Cheng, Ming. 2000

机译：用于开环聚合的新型高活性锌（II）基催化剂：立体有规可生物降解聚合物的合成。
6. Application of Diethylzinc/Propyl Gallate Catalytic System for Ring-Opening Copolymerization of rac-Lactide and ε-Caprolactone [O] . Rafał Wyrębiak, Ewa Oledzka, Ramona Figat, 2019

机译：二乙基锌/没食子酸丙酯催化体系在外消旋丙交酯和ε-己内酯开环共聚中的应用
7. Highly Active Yttrium Catalysts for the Ring-Opening Polymerization of ε-Caprolactone and δ-Valerolactone [O] . Xinke Wang, Jonathan L. Brosmer, Arnaud Thevenon, 2015

机译：高活性的钇催化剂，用于ε-己内酯的开环聚合和δ-戊酮

Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

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