A planar chiral[2.2]paracyclophane derived N-heterocyclic stannylene

Piel I.; Dickschat J.V.; Pape T.; Hahn F.E.; Glorius F.

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A planar chiral[2.2]paracyclophane derived N-heterocyclic stannylene

机译：平面手性[2.2]对环环烷衍生的N-杂环亚锡基

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The reaction of pseudo-ortho-4, 12-N, N′-diphenyldiamino-[2.2]paracyclophane((±)-3)with Sn[N(SiMe _3)_2]_2 results in the formation of the monomeric planar chiral N-heterocyclic stannylene(±)-4, featuring a unique[2.2]paracyclophane backbone, which has been characterized by an X-ray diffraction study.

机译：准邻位4，12-N，N'-二苯基二氨基-[2.2]对环phane（（±）-3）与Sn [N（SiMe _3）_2] _2的反应导致单体平面手性N的形成-杂环亚锡（±）-4，具有独特的[2.2]对环烷骨架，已通过X射线衍射研究表征。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第45期|共3页
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Piel I.; Dickschat J.V.; Pape T.; Hahn F.E.; Glorius F.;
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1. A planar chiral[2.2]paracyclophane derived N-heterocyclic stannylene [J] . Piel I., Dickschat J.V., Pape T., Dalton transactions: An international journal of inorganic chemistry . 2012,第45期

机译：平面手性[2.2]对环环烷衍生的N-杂环亚锡基
2. Synthesis of novel macrocyclic planar chiral carbene-Ag complexes derived from [2.2]paracyclophane for Rh-catalyzed asymmetric 1,2-additions of arylboronic acids to aromatic aldehydes [J] . Chen Jianqiang, Yang Shaobo, Chen Zhen, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2015,第5a6期

机译：衍生自[2.2]对环烷的新型大环平面手性卡宾-银配合物用于Rh催化芳基硼酸向芳族醛的不对称1,2-加成
3. Planar chiral triazole-based phosphanes derived from [2.2]paracyclophane and their activity in suzuki coupling reactions [J] . Glover J.E., Martin D.J., Plieger P.G., European journal of organic chemistry . 2013,第9期

机译：衍生自[2.2]对环环烷的平面手性三唑基膦及其在铃木偶联反应中的活性
4. NLO properties of formyl-methoxy derivatives of 2.2paracyclophane containing the donor group in different positions [C] . Lada N. Puntus, Kyrill Yu. Suponitsky, Dmitrii Antonov, Conference on Optical Materials and Biomaterials in Security and Defence Systems Technology;Conference on Optics and photonics for counterterrorism, crime fighting and defence . 2014

机译：在不同位置含有供体基团的2.2对环环烷的甲酰基-甲氧基衍生物的NLO性质
5. Copper catalyzed cyclopropanation using chiral [2.2]paracyclophane ligands and activation of naphthalenes toward catalytic hydrogenation by coordination of metal moieties. [D] . Masterson, Douglas Scott. 1999

机译：铜催化使用手性[2.2]对环磷烯配体的环丙烷化反应，并通过金属部分的配合将萘活化为催化氢化反应。
6. Synthesis of New Planar-Chiral Linked 2.2Paracyclophanes-N-(2.2-Paracyclophanylcarbamoyl)-4-(2.2Paracyclophanylcarboxamide 2.2Paracyclophanyl-Substituted Triazolthiones and -Substituted Oxadiazoles [O] . Ashraf A. Aly, Stefan Bräse, Alaa A. Hassan, 2020

机译：合成新平面 - 手性连接2.2截谱 - N - （2.2 -Alaryclophanylcarbamoyl）-4 - （2.2截晶蛋白基甲酰胺2.2截晶粒子取代的三唑基和 - 取代的恶唑
7. Front Cover Picture: Multigram‐Scale Kinetic Resolution of 4‐Acetyl2.2Paracyclophane via Ru‐Catalyzed Enantioselective Hydrogenation: Accessing 2.2Paracyclophanes with Planar and Central Chirality (Adv. Synth. Catal. 11/2021) [O] . Christoph Zippel, Zahid Hassan, Ahmad Qais Parsa, 2021

机译：前封面图片：通过Ru催化的映选择性氢化的4-乙酰基的Multigram-Scalic Quicclophane：使用Planar和中枢性手性（Synth。Catal.12221）的ru-Catereded映选择性氢化：进入2.2截谱均匀（ADC。Catal。11/2021）
8. Organotransition-Metal Metallacarboranes. 8. Mono-, Di-, and Triiron Polyarene Sandwich Complexes of Et2C2B4H4(2-) Containing Fluorene, 9,10-Dihydroanthracene, or (2.2)Paracyclophane Ligands [R] . Spencer, J. T., Grimes, R. N. 1987

机译：有机过渡 - 金属金属碳硼烷。 8.含有芴，9,10-二氢蒽或（2.2）对环芳烷配体的Et2C2B4H4（2-）的单 - ，二 - 和三铁聚芳烃夹心复合物

A planar chiral[2.2]paracyclophane derived N-heterocyclic stannylene

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