Copper perchlorate and tetrafluoridoborate compounds with the ligand 1,4,5-triazanaphthalene. Gradual transformation of mononuclear Cu(ii) compounds via polynuclear mixed-valence Cu(ii)/Cu(i) species to dinuclear Cu(i); Syntheses, characterizations and X-ray structures

Van Albada G.A.; Mutikainen I.; Ghazzali M.; Al-Farhan K.; Reedijk J.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Copper perchlorate and tetrafluoridoborate compounds with the ligand 1,4,5-triazanaphthalene. Gradual transformation of mononuclear Cu(ii) compounds via polynuclear mixed-valence Cu(ii)/Cu(i) species to dinuclear Cu(i); Syntheses, characterizations and X-ray structures

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Copper perchlorate and tetrafluoridoborate compounds with the ligand 1,4,5-triazanaphthalene. Gradual transformation of mononuclear Cu(ii) compounds via polynuclear mixed-valence Cu(ii)/Cu(i) species to dinuclear Cu(i); Syntheses, characterizations and X-ray structures

机译：高氯酸铜和四氟硼酸铜化合物与配体1,4,5-三氮杂萘。单核Cu（ii）化合物通过多核混合价Cu（ii）/ Cu（i）物质逐渐转变为双核Cu（i）;合成，表征和X射线结构

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When the ligand 1,4,5-triazanaphthalene (abbreviated as tan) is reacted with Cu(ii) BF _4 ~- and ClO _4 ~- salts, a variety of mononuclear compounds has been found, all with the [Cu(tan) _4] unit and varying amounts of weakly coordinating axial ligands and lattice solvents. Reproducible compounds formed include two purple compounds, analyzing as [Cu(tan) _4](ClO _4) _2(CH _3OH) _2(H _2O) (1) and [Cu(tan) _4] (BF _4) _2(CH _3OH) _(1.5)(H _2O) (3), and two blue compounds, analyzing as [Cu(tan) _4](ClO _4) _2(H _2O) _2 (2) and [Cu(tan) _4] _2(BF _4) _2(H _2O) _2 (4). Upon standing at room temperature, red-coloured, mixed-valence dinuclear-based 3D coordination polymers are formed by conversion of the purple/blue products, of which [Cu _2(tan) _4] n(BF _4) _(3n) (5) and the isomorphic methanol-water adduct [Cu(tan) _4] n(BF _4) _(3n)(CH _3OH) _n(H _2O) _(5n) (5A) are presented in this paper. In addition a fully reduced dinuclear Cu(i) compound of formula [Cu _2(tan) _3(ClO _4) _2] (7) has been observed, and structurally characterized, as a rare three-blade propeller structure, with a Cu-Cu distance of 2.504 ?.

机译：当配体1,4,5-三氮杂萘（缩写为tan）与Cu（ii）BF_4〜-和ClO_4〜-盐反应时，发现了各种单核化合物，全部与[Cu（tan） _4]单位和数量不等的弱配位轴向配体和晶格溶剂。形成的可再现化合物包括两种紫色化合物，分析为[Cu（tan）_4]（ClO _4）_2（CH _3OH）_2（H _2O）（1）和[Cu（tan）_4]（BF _4）_2（CH _3OH））_（1.5）（H _2O）（3）和两种蓝色化合物，分析为[Cu（tan）_4]（ClO _4）_2（H _2O）_2（2）和[Cu（tan）_4] _2（ BF _4）_2（H _2O）_2（4）。在室温下放置时，通过转换紫色/蓝色产物形成红色的，基于混合价双核双价3D配位聚合物，其中[Cu _2（tan）_4] n（BF _4）_（3n）（ 5）和同构甲醇-水加合物[Cu（tan）_4] n（BF _4）_（3n）（CH _3OH）_n（H _2O）_（5n）（5A）呈现。此外，已观察到完全还原的式[Cu _2（tan）_3（ClO _4）_2]（7）的双核Cu（i）化合物，并在结构上表征为稀有的三叶螺旋桨结构，具有Cu- Cu的距离为2.504Ω。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第15期|共9页
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Van Albada G.A.; Mutikainen I.; Ghazzali M.; Al-Farhan K.; Reedijk J.;
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1. Copper perchlorate and tetrafluoridoborate compounds with the ligand 1,4,5-triazanaphthalene. Gradual transformation of mononuclear Cu(ii) compounds via polynuclear mixed-valence Cu(ii)/Cu(i) species to dinuclear Cu(i); Syntheses, characterizations and X-ray structures [J] . Van Albada G.A., Mutikainen I., Ghazzali M., Dalton transactions: An international journal of inorganic chemistry . 2012,第15期

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2. OD Cu(II) and ID mixed-valence Cu(I)/Cu(II) coordination compounds based on mixed ligands: Syntheses, structures and catalytic thermal decomposition for HMX [J] . Jingping Wei, Dan Zhang, Qi Yang Inorganic Chemistry Communications . 2013,第Null期

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Copper perchlorate and tetrafluoridoborate compounds with the ligand 1,4,5-triazanaphthalene. Gradual transformation of mononuclear Cu(ii) compounds via polynuclear mixed-valence Cu(ii)/Cu(i) species to dinuclear Cu(i); Syntheses, characterizations and X-ray structures

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