In situ ligand formation in the synthesis of an octanuclear dysprosium 'double cubane' cluster displaying single molecule magnet features

Chesman A.S.R.; Turner D.R.; Moubaraki B.; Murray K.S.; Deacon G.B.; Batten S.R.

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In situ ligand formation in the synthesis of an octanuclear dysprosium 'double cubane' cluster displaying single molecule magnet features

机译：显示单分子磁体特征的八核“双古巴”簇的合成中原位配体形成

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The nucleophilic addition of methanol and water to the dicyanonitrosomethanide anion, resulting in the formation of cyano(imino(methoxy)methyl)nitrosomethanide (cmnm) and carbamoylcyanonitrosomethanide (ccnm), respectively, is used as a means of in situ ligand synthesis during the formation of [Dy _8(OH) _6(OMe) _6(cmnm) _(10)(ccnm) _2(H _2O) _2(MeOH) _2] (1). This is the first time these reactions have been observed to be promoted by the presence of a lanthanoid ion. The core of the octanuclear cluster consists of two cubane moieties ([Dy _4(OH) _3(OMe)]), bridged by four methoxide ligands to form a central [Dy _8(OH) _6(OMe) _6] moiety. The complex displays magnetic properties that are indicative of probable single molecule magnet features.

机译：将甲醇和水亲核加成到二氰基硝基亚砷酸根阴离子上，分别形成氰基（亚氨基（甲氧基）甲基）硝基亚甲基磺酸根（cmnm）和氨基甲酰基氰基硝基硝基亚甲基磺酸根（ccnm），作为形成过程中原位配体合成的手段[Dy _8（OH）_6（OMe）_6（cmnm）_（10）（ccnm）_2（H _2O）_2（MeOH）_2的摩尔数）（1）。这是第一次观察到镧系离子的存在促进了这些反应。八核簇的核心由两个古巴部分（[Dy _4（OH）_3（OMe）]）组成，由四个甲醇配体桥接形成中心[Dy _8（OH）_6（OMe）_6]部分。该复合物显示出指示可能的单分子磁体特征的磁性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第13期|共7页
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Chesman A.S.R.; Turner D.R.; Moubaraki B.; Murray K.S.; Deacon G.B.; Batten S.R.;
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1. In situ ligand formation in the synthesis of an octanuclear dysprosium 'double cubane' cluster displaying single molecule magnet features [J] . Chesman A.S.R., Turner D.R., Moubaraki B., Dalton transactions: An international journal of inorganic chemistry . 2012,第13期

机译：显示单分子磁体特征的八核“双古巴”簇的合成中原位配体形成
2. Single-molecule magnet behavior in an octanuclear dysprosium(III) aggregate inherited from helical triangular Dy-3 SMM-building blocks [J] . Zhang Li, Zhang Peng, Zhao Lang, Dalton transactions: An international journal of inorganic chemistry . 2016,第26期

机译：从螺旋三角形Dy-3 SMM构件继承的八核（III）聚集体中的单分子磁体行为
3. Quadruple-CO_3~(2-) bridged octanuclear dysprosium(Ⅲ) compound showing single-molecule magnet behaviour [J] . Haiquan Tian, Lang Zhao, Yun-Nan Guo, Chemical Communications . 2012,第5期

机译：具有单分子磁体行为的四元CO_3〜（2-）桥联八核clear（Ⅲ）化合物
4. Rational Conception of Dysprosium-based Complex featuring Different Single-Molecule Magnets: Magnetic Interaction and Isotopic Effects [C] . Fabrice Pointillart, Boris Le Guennic, Olivier Cador Rare Earth Research Conference . 2019

机译：基于镝的复合物的理性概念，具有不同的单分子磁铁：磁性相互作用和同位素效应
5. Synthesis and characterization of cyanide-bridged materials: From cluster-expanded Prussian blue analogues to single-molecule magnets. [D] . Shores, Matthew Paul. 2002

机译：氰化物桥接材料的合成和表征：从簇扩展的普鲁士蓝类似物到单分子磁体。
6. Tetrathiafulvalene-Based Helicene Ligand in the Designof a Dysprosium Field-Induced Single-Molecule Magnet [O] . Fabrice Pointillart, *, Jiang-Kun Ou-Yang, -1

机译：设计中基于四硫富瓦烯的螺旋烯配体Field场感应单分子磁体的制备
7. Synthesis, structure, magnetic and luminescence properties of two dysprosium single-molecule magnets based on phenoxide dye ligands [O] . Jérôme Long, Alexander N. Selikhov, Ekaterina Mamontova, 2020

机译：基于苯氧化物染料配体的两种镝单分子磁体的合成，结构，磁性和发光性能

In situ ligand formation in the synthesis of an octanuclear dysprosium 'double cubane' cluster displaying single molecule magnet features

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