Binding and activation of nitrite and nitric oxide by copper nitrite reductase and corresponding model complexes

Merkle A.C.; Lehnert N.

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Binding and activation of nitrite and nitric oxide by copper nitrite reductase and corresponding model complexes

机译：亚硝酸铜还原酶和相应模型配合物对亚硝酸盐和一氧化氮的结合和活化

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The reduction of nitrite to nitric oxide in dissimilatory denitrification is carried out by copper nitrite reductases (CuNIRs) via a type 2 copper site. Extended studies on CuNIRs in combination with model complexes have allowed for the establishment of two potential mechanisms for this transformation. Recent experimental and computational results have revealed further details of this process. In addition, the interaction of NO with copper sites has recently gained much attention. This review discusses recent results in the context of the known coordination chemistry of CuNIRs.

机译：在亚硝化反硝化中，亚硝酸盐还原为一氧化氮是通过亚硝酸铜还原酶（CuNIR）通过2型铜位进行的。对CuNIR与模型复合物结合的扩展研究已经为这种转化建立了两种潜在的机制。最近的实验和计算结果揭示了该过程的更多细节。另外，NO与铜位点的相互作用最近引起了很多关注。这篇综述在已知的CuNIR配位化学的背景下讨论了最近的结果。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第12期|共14页
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Merkle A.C.; Lehnert N.;
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1. Binding and activation of nitrite and nitric oxide by copper nitrite reductase and corresponding model complexes [J] . Merkle A.C., Lehnert N. Dalton transactions: An international journal of inorganic chemistry . 2012,第12期

机译：亚硝酸铜还原酶和相应模型配合物对亚硝酸盐和一氧化氮的结合和活化
2. SYNTHETIC MODELING OF NITRITE BINDING AND ACTIVATION BY REDUCED COPPER PROTEINS - CHARACTERIZATION OF COPPER(I)-NITRITE COMPLEXES THAT EVOLVE NITRIC OXIDE [Review] [J] . Halfen JA, Mahapatra S, Wilkinson EC, Journal of the American Chemical Society . 1996,第4期

机译：减少的铜蛋白对亚硝酸盐结合和活化的合成模拟-逐渐释放出一氧化氮的铜（I）-亚硝酸盐络合物的表征[综述]
3. The binding of nitric oxide at the Cu(I) site of copper nitrite reductase and of inorganic models:DFT calculations of the energetics and EPR parameters of side-on and end-on structures [J] . Ganga Periyasamy, Mahesh Sundararajan, Ian H.Hillier Physical chemistry chemical physics: PCCP . 2007,第20期

机译：一氧化氮在亚硝酸铜还原酶的Cu（I）位点和无机模型上的结合：侧向和末端结构的能量和EPR参数的DFT计算
4. Streptococcus mutans Has a Gene Encoding Nitrite Reductase and Generates Nitric Oxide in the Oral Cavity [C] . E.F. Sato, T. Choudhury, M. Inoue International Society for Free Radical Research . 2006

机译：链球菌异常具有编码亚硝酸盐还原酶的基因，并在口腔中产生一氧化氮
5. Reaction of nitric oxide species with metal centered macrocyclic complexes: (1) Catalytic oxygen atom transfer reaction using water-soluble ferric porphyrin complexes and nitrite ion, and (2) Nitric oxide reaction with derivatized cupric cyclam complexes [D] . Khin, Chosu 2008

机译：一氧化氮物质与以金属为中心的大环配合物的反应：（1）使用水溶性三价铁卟啉配合物和亚硝酸根离子的催化氧原子转移反应，以及（2）衍生化的铜环素配合物的一氧化氮反应
6. Nitric Oxide Production from Nitrite Reduction and Hydroxylamine Oxidation by Copper-containing Dissimilatory Nitrite Reductase (NirK) from the Aerobic Ammonia-oxidizing Archaeon Nitrososphaera viennensis [O] . Shun Kobayashi, Daisuke Hira, Keitaro Yoshida, 2018

机译：需氧氨氧化古细菌Nitrososphaera viennensis的含铜亚硝酸盐还原酶（NirK）通过亚硝酸盐还原和羟胺氧化生产一氧化氮
7. The energy-conserving nitric-oxide-reductase system in Paracoccus denitrificans. Distinction from the nitrite reductase that catalyses synthesis of nitric oxide and evidence from trapping experiments for nitric oxide as a free intermediate during denitrification [O] . Grant J. CARR, M. Dudley PAGE, Stuart J. FERGUSON 1989

机译：裂缝杆菌脱氮机中的节能硝基氧化物还原酶体系。从亚硝酸盐还原酶中区分催化一氧化氮的合成和通过捕获一氧化氮的实验作为反硝化中间体的实验

Binding and activation of nitrite and nitric oxide by copper nitrite reductase and corresponding model complexes

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