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Schizophrenic electrons in ruthenium-based oxides

机译:钌基氧化物中的精神分裂电子

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摘要

Ruthenium and oxygen form many ternary compounds in which the Ru 4d states and O 2p states are strongly hybridized. In some such compounds, this hybridization leads to the loss of local magnetic moment character for the Ru, and in others it does not. The factors that determine which is the case are often subtle and poorly understood. The richness of structure types seen in ternary Ru oxides leads to a corresponding richness in electronic and magnetic properties. This article briefly describes the author's current views on these materials.
机译:钌和氧形成许多三元化合物,其中Ru 4d态和O 2p态强烈杂交。在某些此类化合物中,这种杂交导致Ru失去局部磁矩特性,而在其他情况下则不会。确定哪种情况的因素通常是微妙的,并且了解甚少。在三元Ru氧化物中看到的结构类型的丰富导致相应的电子和磁性性质的丰富。本文简要介绍了作者对这些材料的当前观点。

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