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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Metal-oxygen-metal arrays in lamellar hybrid materials:Cobalt and manganese 4-cyclohexene-l,2-dicarboxylates
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Metal-oxygen-metal arrays in lamellar hybrid materials:Cobalt and manganese 4-cyclohexene-l,2-dicarboxylates

机译：层状杂化材料中的金属-氧-金属阵列：4-环己烯-1,2-二羧酸钴和锰

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摘要

We have obtained three layered hybrid materials from the hydrothermal reaction of 4-cyclohexene-l,2-dicarboxylic acid with Co and Mn salts:Co(C_8H_8O_4)[1],Mn(H_2O)(C_8H_8O_4)[2],and Mn_4(H_2O)(C_8H_8O_4)_4-0.3(H_2O)[3].The structures for all materials were solved by single-crystal XRD([1] PI,a = 4.805(2)k,b = 6.650(3)A,c = 12.960(6)A,a = 98.285(7)deg ,beta = 98.986(7)deg ,7 = 95.689(7)deg ,V= 401.6(3)A~3,R,= 0.0438;[2] P2,/c,a = 11.151(2)A,b = 11.330(2)A,c = 7.6560(15)A,beta= 108.813(3)deg ,V= 915.6(3)A~3,R,= 0.0412;[3] PI,a = 11.412(3)k,b= 12.136(4)A,c = 13.809(4)A,a = 104.703(6)deg ,beta= 103.207(6)deg ,gamma = 92.468(5)deg ,V= 1790.6(9)A~3,R,= 0.1056).While all three structures are two-dimensional overall,the metal-oxygen-metal dimensionality within the layers varies from isolated metal atoms in the case of [1] to ID ribbons of vertex sharing MnO_6 octahedra [2] and 2D arrays of edge-and vertex-sharing polyhedra in [3].
机译：我们通过4-环己烯-1,2-二羧酸与Co和Mn盐的水热反应获得了三层杂化材料：Co（C_8H_8O_4）[1]，Mn（H_2O）（C_8H_8O_4）[2]和Mn_4（ H_2O）（C_8H_8O_4）_4-0.3（H_2O）[3]。通过单晶XRD（[1] PI，a = 4.805（2）k，b = 6.650（3）A，c求解所有材料的结构= 12.960（6）A，a = 98.285（7）deg，beta = 98.986（7）deg，7 = 95.689（7）deg，V = 401.6（3）A〜3，R，= 0.0438; [2] P2 ，/ c，a = 11.151（2）A，b = 11.330（2）A，c = 7.6560（15）A，beta = 108.813（3）deg，V = 915.6（3）A〜3，R，= 0.0412 ; [3] PI，a = 11.412（3）k，b = 12.136（4）A，c = 13.809（4）A，a = 104.703（6）deg，beta = 103.207（6）deg，gamma = 92.468（ 5）deg，V = 1790.6（9）A〜3，R，= 0.1056。）虽然所有三个结构都是二维的，但在[情况下，层中的金属-氧-金属维数与孤立的金属原子不同1]到共享MnO_6八面体[2]的顶点的ID带和[3]中的边缘和顶点共享多面体的2D阵列。

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