Electrochemistry of a labile average-valence dicopper system

Joanne Coyle; Alison J. Downard; Jane Nelson; Vickie McKee; Charles J. Harding; Regine Herbst-Irmer

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Electrochemistry of a labile average-valence dicopper system

机译：不稳定平均价双铜系统的电化学

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Electrochemical studies on an average-valent dicopper cryptate demonstrate the existence of a solvent-assisted disproportionation in acetonitrile, which is absent in water. The existence of this process was confirmed via absorption spectroscopy, which allowed the evaluation of thermodynamic parameters. The disproportionation equilibrium is enthalpically controlled, and the results suggest an upper limit for the bond energy of the one-electron Cu-Cu bond of 200 kJ mol~(-1).

机译：对平均价双铜隐酸盐的电化学研究表明乙腈中存在溶剂辅助歧化，而乙腈在水中不存在。通过吸收光谱法确认了该过程的存在，其允许评估热力学参数。歧化平衡受焓控制，结果表明单电子Cu-Cu键的键能上限为200 kJ mol〜（-1）。

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《Dalton transactions: An international journal of inorganic chemistry》 |2004年第15期|共7页
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Joanne Coyle; Alison J. Downard; Jane Nelson; Vickie McKee; Charles J. Harding; Regine Herbst-Irmer;
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1. Electrochemistry of a labile average-valence dicopper system [J] . Joanne Coyle, Alison J. Downard, Jane Nelson, Dalton transactions: An international journal of inorganic chemistry . 2004,第15期

机译：不稳定平均价双铜系统的电化学
2. Raman spectroscopy of three average-valence dicopper cryptates: Evidence for copper-copper bonding [J] . Al-Obaidi A., Coyle J., Coates CG., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第14期

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Electrochemistry of a labile average-valence dicopper system

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