Highly efficient binding of trivalent f-elements from acidic media with a C_3-symmetric tripodal ligand containing diglycolamide arms

Kornelia Matloka; Artem Gelis; Monica Regalbuto; George Vandegrift; MichaeU.Scott

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Highly efficient binding of trivalent f-elements from acidic media with a C_3-symmetric tripodal ligand containing diglycolamide arms

机译：来自酸性介质的三价f元素与含有二甘醇酰胺臂的C_3对称三脚架配体的高效结合

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摘要

Tripodal chelates bearing three diglycolamide units precisely arranged on a triphenoxymethane platform were synthesized to mimic the preferred tricapped trigonal prismatic geometry favored by lanthanides with oxygen donor ligands,and the ligand binds heavier lanthanides very efficiently in acidic media.

机译：合成了带有精确排列在三苯氧甲烷平台上的三个二甘醇酰胺单元的三脚架螯合物，以模拟镧系元素与供氧体配体所偏爱的优选三棱三棱柱形几何结构，并且该配体在酸性介质中非常有效地结合了较重的镧系元素。

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《Dalton transactions: An international journal of inorganic chemistry》 |2005年第23期|共3页
作者
Kornelia Matloka; Artem Gelis; Monica Regalbuto; George Vandegrift; MichaeU.Scott;
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1. Highly efficient binding of trivalent f-elements from acidic media with a C_3-symmetric tripodal ligand containing diglycolamide arms [J] . Kornelia Matloka, Artem Gelis, Monica Regalbuto, Dalton transactions: An international journal of inorganic chemistry . 2005,第23期

机译：来自酸性介质的三价f元素与含有二甘醇酰胺臂的C_3对称三脚架配体的高效结合
2. Highly Efficient Extraction of Trivalent f-Cations Using Several N-Pivot Tripodal Diglycolamide Ligands in an Ionic Liquid: The Role of Ligand Structure on Metal Ion Complexation [J] . Ansari Seraj A., Mohapatra Prasanta K., Verma Parveen K., European journal of inorganic chemistry . 2020,第2期

机译：在离子液体中使用几个N-枢轴三码头二甲磺酰胺配体的高效提取三价F阳离子：配体结构对金属离子络合的作用
3. Highly Efficient N-Pivot Tripodal Diglycolamide Ligands for Trivalent f-Cations: Synthesis, Extraction, Spectroscopy, and Density Functional Theory Studies [J] . Ansari Seraj A., Mohapatra Prasanta K., Leoncini Andrea, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第13期

机译：高效的N-枢轴三码头北甲酰胺配体，用于三价F阳离子：合成，提取，光谱学和密度泛函理论研究
4. Development of Bidentate Diphosphine Ligands of Highly Active Ru Catalysts for Practical Hydrogenation of Carboxylic Acids [C] . Shota Yoshioka, Masayuki Naruto, Ryoji Noyori 日本化学会春季年会講演予稿集 . 2018

机译：高活性Ru催化剂的二硫代二膦配体的发展，用于羧酸的实际氢化
5. Investigation on the Diluent Effect on Solvent Extraction Processes of Trivalent f-Elements by Acidic Di-Alkyl Organophosphorus Extractants [D] . Lécrivain, Thibaut Jean-Michel Lucien 2018

机译：酸性二烷基有机磷萃取剂对三价f元素溶剂萃取过程的稀释作用研究
6. Optimizing PN-Bidentate Ligands for Oxidative Gold Catalysis: Highly Efficient Intermolecular Trapping of α-Oxo Gold Carbenes by Carboxylic Acids [O] . Kegong Ji, Yulong Zhao, Liming Zhang -1

机译：优化用于氧化金催化的PN-二齿配体：羧酸对α-氧代羰基金的高效分子间捕集
7. Remarkable Enhancement in Extraction of Trivalent fBlock Elements Using a Macrocyclic Ligand with Four Diglycolamide Arms: Synthesis, Extraction, and Spectroscopic and Density Functional Theory Studies [O] . -1

机译：使用宏环配体提取三价Fblock元件的显着增强，其具有四甲酰胺臂：合成，提取和光谱和密度泛函理论研究

Highly efficient binding of trivalent f-elements from acidic media with a C_3-symmetric tripodal ligand containing diglycolamide arms

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