A hardwon dirhodium paddlewheel with guanidinate type(hpp)bridging ligands

John F.Berry; F.Albert Cotton; Penglin Huang; Carlos A.Murillo; Xiaoping Wang

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A hardwon dirhodium paddlewheel with guanidinate type(hpp)bridging ligands

机译：具有胍盐型（hpp）桥联配体的硬质迪氏桨轮

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We report a dirhodium paddlewheel compound which has an Rh_2~(5+)core enveloped by four guanidinate ligands and an axially coordinated bromine atom;Rh_2(hpp)_4Br crystallizes as a 1-D chain with a Rh-Rh distance of 2.430(3)e and a Rh-Rh bond order of 1.5(hpp=the anion of 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2a]pyrimidine).

机译：我们报告了一个ho铑化合物，其Rh_2〜（5+）核心被四个胍盐配体和一个轴向配位的溴原子包裹; Rh_2（hpp）_4Br结晶为1-D链，Rh-Rh距离为2.430（3））e和1.5的Rh-Rh键序（hpp = 1,3,4,6,7,8-六氢-2H-嘧啶[1,2a]嘧啶的阴离子）。

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《Dalton transactions: An international journal of inorganic chemistry》 |2005年第23期|共3页
作者
John F.Berry; F.Albert Cotton; Penglin Huang; Carlos A.Murillo; Xiaoping Wang;
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1. A hardwon dirhodium paddlewheel with guanidinate type(hpp)bridging ligands [J] . John F.Berry, F.Albert Cotton, Penglin Huang, Dalton transactions: An international journal of inorganic chemistry . 2005,第23期

机译：具有胍盐型（hpp）桥联配体的硬质迪氏桨轮
2. Acetamidate-bridged paddlewheel dirhodium complex sandwiched by mononuclear platinum complexes with axial metal-metal bonds affording neutral heterometallic one-dimensional alignments [J] . Uemura Kazuhiro, Yamada Tomofumi, Kanbara Toru, Inorganica Chimica Acta . 2015,第Null期

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3. Dirhodium Paddlewheel with Functionalized Carboxylate Bridges: New Building Block for Self-Assembly and Immobilization on Solid Support [J] . D. Krishna Kumar, Alexander S. Filatov, Margaret Napier, Inorganic Chemistry . 2012,第8期

机译：带有功能性羧酸盐桥的Dirhodium桨轮：用于自组装和固定在固体支持物上的新构件
4. Synthesis and Reactions of Hydroxo-bridged Dirhodium Complex Bearing Diphosphinidenecyclobutene Ligand (DPCB) [C] . Akito Hayashi, Yuichiro Mutoh, Masaaki Okazaki Symposium on Organometallic Chemistry . 2006

机译：羟基桥型甲醛含量二磷苯二丁烯配体（DPCB）的合成与反应
5. Gravimetrically characterizable common alkali reducing agents and ligand design of a new electron rich guanidinate. [D] . Castillo Noris, Efrain Maximiliano. 2016

机译：重量分析法表征的通用碱还原剂和新型富电子胍盐的配体设计。
6. Synthesis Characterization Absorption Properties and Electronic Structures of Paddlewheel-Type Dirhodium(II) Tetra-μ-(n-naphthoate) Complexes: An Experimental and Theoretical Study [O] . Yusuke Kataoka, Raiki Fukumoto, Natsumi Yano, 2019

机译：桨轮型四（n-萘甲酸）吡啶鎓（II）吡啶鎓（II）配合物的合成表征吸收性质和电子结构：实验和理论研究
7. Expanded Use of Bicyclic Guanidinate Ligands in Dimetal Paddlewheel Compounds [O] . Young Mark D. 2010

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A hardwon dirhodium paddlewheel with guanidinate type(hpp)bridging ligands

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