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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Templated metal-organic frameworks:synthesis,structures,thermal properties and solid-state transformation of two novel calcium-adipate frameworks
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Templated metal-organic frameworks:synthesis,structures,thermal properties and solid-state transformation of two novel calcium-adipate frameworks

机译:模板化金属有机骨架:两种新型己二酸钙骨架的合成,结构,热性质和固相转化

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摘要

Two novel calcium-adipate framework materials have been synthesized hydrothermally.GWMOF-7([Ca(C_6H_8O_4)(H_2O)_2]-(C_(10)H_8N_2))and GWMOF-8([Ca(C_6H_8O_4)(H_2O),]-(C_(12)H(12)N_2))both formed three-dimensional structures and were characterized with single-crystal X-ray diffraction,powder X-ray diffraction,IR spectroscopy and elemental analysis.Thermal properties were also studied with thermogravimetric analysis,and show that these structures undergo a solid-state transformation into a denser three-dimensional framework.
机译:水热合成了两种新型的己二酸钙骨架材料。 -(C_(12)H(12)N_2))均形成三维结构,并通过单晶X射线衍射,粉末X射线衍射,IR光谱和元素分析进行​​了表征。分析,并表明这些结构经历了固态转变为更密集的三维框架。

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