Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15]

Carr MJ; Londesborough MGS; Mcleod ARH; Kennedy JD

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15]

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Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15]

机译：宏观多面体含硼簇化学。来自S2B17H17的金属硫杂环丁烷：[[eta（6）-（MeC6H4Pr）-Pr-iso）RuS2B16H16]和[[eta（6）-（MeC6H4Pr）-Pr-iso）RuS2B15H15]的分离和表征

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Deprotonation of [S2B17H17] 1 with NaH and subsequent reaction with [{RuCl2(eta(6)-MeC6H4 Pr-iso)}(2)] gives new nineteen-vertex [(eta(6)- MeC6H4 Pr-iso) RuS2B16H16] 2, with a nido {SB9} unit and an arachno-type {RuSB9} unit conjoined with a B - B edge in common, and new eighteen-vertex [(eta(6)-MeC6H4 Pr-iso) RuS2B15H15] 3 with a nido {RuSB9} subcluster fused via a common B - B edge to a nido {B-8} subcluster that is additionally linked exo to the {RuSB9} unit by a bridging sulfur atom that is held endo to the {B-8} unit.

机译：[S2B17H17] 1用NaH脱质子，然后与[{RuCl2（eta（6）-MeC6H4 Pr-iso）}（2）反应）得到新的十九个顶点[（eta（6）-MeC6H4 Pr-iso）RuS2B16H16] 2，具有一个nido {SB9}单元和一个Arachno型{RuSB9}单元，共同与一个B-B边相连，并且新的18顶点[（eta（6）-MeC6H4 Pr-iso）RuS2B15H15] 3与nido {RuSB9}子簇通过一个公共的B-B边缘与nido {B-8}子簇融合，该子簇另外通过{B-8}单元内的桥连硫原子与exo连接到{RuSB9}单元。。

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《Dalton transactions: An international journal of inorganic chemistry》 |2006年第30期|共3页
作者
Carr MJ; Londesborough MGS; Mcleod ARH; Kennedy JD;
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正文语种 eng
中图分类无机化学;
关键词
ANION; METALLABORANES; ARCHITECTURE; THIABORANE; INSERTION;

机译：阴离子;金属硼烷;建筑;硫代硼烷;插入;

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1. Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15] [J] . Carr MJ, Londesborough MGS, Mcleod ARH, Dalton transactions: An international journal of inorganic chemistry . 2006,第30期

机译：宏观多面体含硼簇化学。来自S2B17H17的金属硫杂环丁烷：[[eta（6）-（MeC6H4Pr）-Pr-iso）RuS2B16H16]和[[eta（6）-（MeC6H4Pr）-Pr-iso）RuS2B15H15]的分离和表征
2. MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY.A METALLATHIABORANE FROM S_2B_(17)H_(17): ISOLATION AND CHARACTERISATION OF [(PMe_2Ph)_2PtS_2B_(16)H_(16)];A neo-arachno TEN-VERTEX CLUSTER SHAPE,AND THE CONSTITUTION OF THE [arachno-B_(10)H_(15)- AN [J] . Jonathan Bould, John D.KENNEDY, Michael J.CARR, Collection of Czechoslovak Chemical Communications . 2005,第4期

机译：S_2B_（17）H_（17）中的金属多面体硼化学簇合物：[（PMe_2Ph）_2PtS_2B_（16）H_（16）]的分离和表征的[arachno-B_（10）H_（15）-AN
3. Macropolyhedral boron-containing cluster chemistry. [PtMe2(PMe2Ph)(2)] as a cluster metallating agent. Isolation and characterisation of nineteen-vertex [(PMe2Ph)HPt-eta(4)-syn-B18H19(PMe2Ph)] and eighteen-vertex [(PMe2Ph)(2)PtS2B15H14(NHCOMe] [J] . Kaur P., Perera SD., Cooke PA., Journal of Organometallic Chemistry . 1998,第2期

机译：宏观多面体含硼簇化学。 [PtMe2（PMe2Ph）（2）]作为团簇金属化剂。十九个顶点[（PMe2Ph）HPt-eta（4）-syn-B18H19（PMe2Ph）]和十八个顶点[（PMe2Ph）（2）PtS2B15H14（NHCOMe）的分离和表征
4. Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well Defined Polyoxo Rare Earth Metal Clusters [C] . Takanori Shima, Zhaomin Hou Symposium on Organometallic Chemistry . 2006

机译：四核稀土金属聚醇配合物氢化一氧化碳。乙烯选择性形成和良好定义的Polyoxo稀土金属簇分离
5. Redox active metal-sulfide clusters and computer-assisted instructional lessons on transition metal chemistry. [D] . Gammon, Steven Drew. 1989

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6. Isolation and characterization of the human chorionic gonadotropin beta subunit (CG beta) gene cluster: regulation of transcriptionally active CG beta gene by cyclic AMP. [O] . J L Jameson, C M Lindell 1988

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7. Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex(eta(5)-C5Me5) HIrB18H19(PMe2Ph) and the related carbene complex (eta(5)-C5Me5)HIrB18H19{C(NHMe)(2)}ud [O] . Shea S.L., Jelinek T., Perera S.D., 2004

机译：大多面体含硼簇化学。配体诱导的集群间键合亲密度的双电子变化。 19个顶点（η（5）-C5me5）HIrB18H19（pme2ph）和相关卡宾配合物（η（5）-C5me5）HIrB18H19 {C（NHme）（2）}的结构
8. Metal Atom Synthesis of Metallaboron Clusters. 7. Synthesis and Structural Characterization of an Open-Cage Metallathiaborane Cluster Having a Triple-Decker Structure: 4,6-(Eta-C5H5)2Co2-3,S2B2H2. [R] . Sneddon, L. G. 1985

机译：metallaboron团簇的金属原子合成。 7.具有三层结构的开笼金属硅烷簇的合成和结构表征：4,6-（Eta-C5H5）2Co2-3，s2B2H2。

Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15]

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