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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Ion-polyether coordination complexes: crystalline ionic conductors for clean energy storage
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Ion-polyether coordination complexes: crystalline ionic conductors for clean energy storage

机译:离子-聚醚配位化合物:用于清洁能源存储的结晶离子导体

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摘要

Ion-polyether complexes are the solid state analogues of crown ether and cryptand complexes. They represent a fascinating class of coordination compounds in their own right, with the ability to support ionic conductivity and the potential to be used as electrolytes in all-solid-state rechargeable lithium batteries. Here the recent discovery of ionic conductivity in crystalline ion-polyether complexes, when for 30 years such materials were considered to be insulators, is described, along with their closely related structural chemistry.
机译:离子-聚醚配合物是冠醚和穴状配合物的固态类似物。它们本身具有迷人的一类配位化合物,具有支持离子导电性的能力以及用作全固态可充电锂电池电解质的潜力。这里描述了晶体离子-聚醚络合物中30年来被认为是绝缘体的离子电导率的最新发现,以及与它们密切相关的结构化学。

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