Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As-S anions

Langer R; Shi WF; Rothenberger A

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Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As-S anions

机译：铜介导的叔膦对二硫键的裂解：As-S阴离子的新途径

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摘要

The synthesis of [(PhAs)(2)(mu-S-2)(mu-S)] and its reactions to form novel Cu(I) complexes are reported, together with a new cleavage reaction of disulfides by Cu( I) thiolates and tertiary phosphines.

机译：报道了[（PhAs）（2）（mu-S-2）（mu-S）]的合成及其形成新型Cu（I）配合物的反应，以及Cu（I）对二硫化物的新裂解反应。硫醇盐和叔膦。

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《Dalton transactions: An international journal of inorganic chemistry》 |2006年第37期|共3页
作者
Langer R; Shi WF; Rothenberger A;
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正文语种 eng
中图分类无机化学;
关键词
CAMBRIDGE STRUCTURAL DATABASE; TRANSITION-METAL-COMPLEXES; MOLECULAR-STRUCTURE; CARBONYL-COMPLEXES; CRYSTAL-STRUCTURES; COORDINATION; LIGANDS; REAGENT; CHEMISTRY;

机译：剑桥结构数据库;过渡金属复合物;分子结构;羰基复合物;晶体结构;配位;配体;试剂;化学;

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1. Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As-S anions [J] . Langer R, Shi WF, Rothenberger A Dalton transactions: An international journal of inorganic chemistry . 2006,第37期

机译：铜介导的叔膦对二硫键的裂解：As-S阴离子的新途径
2. Chloride anion transport and copper-mediated DNA cleavage by C-ring functionalized prodigiosenes [J] . Rosa I. Saez Diaz, Jasmine Regourd, Paul V. Santacroce, Chemical Communications . 2007,第26期

机译：C环官能化的pro生素对氯离子的转运和铜介导的DNA裂解
3. Tris(3-hydroxypropyl) phosphine (THPP): A mild, air-stable reagent for the rapid, reductive cleavage of small-molecule disulfides [J] . McNulty James, Krishnamoorthy Venkatesan, Amoroso Dino, Bioorganic and Medicinal Chemistry Letters . 2015,第19期

机译：三（3-羟丙基）膦（THPP）：一种温和的，空气稳定的试剂，用于快速还原还原小分子二硫化物
4. Nucleophilic Substitution of P-Stereogenic Chlorophosphines and Stereoselective Conversions of Diastereomeric Secondary Phosphine Oxides to Tertiary Phosphine [C] . Ye Jingjing, Nie Shaozhen 日本化学会春季年会講演予稿集 . 2018

机译：对二对映射次磷酸氧化氢氧化膦的双层氯磷脂和立体选择性转化的亲核取代
5. Phosphine Catalysis using Allenoates with pro-Nucleophiles or Arylidenes; Development of an Asymetric Phosphine Catalyst; and Allenes as pi-Ligands in Copper-Mediated Cross-Coupling. [D] . Martin, Tioga. 2014

机译：使用烯丙酸酯与亲核亲核试剂或丙烯醛进行膦催化；非对称膦催化剂的开发；在铜介导的交叉偶联中，Al和烯为pi-配体。
6. Loop recognition and copper-mediated disulfide reduction underpin metal site assembly of CuA in human cytochrome oxidase [O] . Marcos N. Morgada, Luciano A. Abriata, Chiara Cefaro, 2015

机译：在人类细胞色素氧化酶中铜的环识别和铜介导的二硫键还原支撑金属位点组装
7. On the Constitution of the Addition Compounds of Tertiary Phosphines and Carbon Disulfide. [O] . K. A. Jensen, P. H. Nielsen, Sture Forsén, 1963

机译：论叔膦和二硫化碳的添加化合物的构造。
8. Poly(Tertiary Phosphines and Arsines). XIV. Some Metal Complexes of Neopentyl Poly (Tertiary Phosphines). [R] . King, R. B., Cloyd, J. C., Reimann, R. H. 1975

机译：聚（叔膦和胂）。十四。一些新戊基聚（叔膦）金属配合物。

Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As-S anions

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