A trinuclear complex containing (MnMnMnIV)-Mn-II-Mn-III, radicals, quinone and chloride ligands potentially relevant to PSII

Mukherjee C; Weyhermuller T; Wieghardt K; Chaudhuri P

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A trinuclear complex containing (MnMnMnIV)-Mn-II-Mn-III, radicals, quinone and chloride ligands potentially relevant to PSII

机译：包含（MnMnMnIV）-Mn-II-Mn-III，自由基，醌和氯化物配体的三核配合物

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摘要

Reaction of MnCl2 with a non-innocent ligand H3L results in an unprecedented mixed-valence trinuclear complex [(MnMnMnIV)-Mn-II-Mn-III( L)( L-center dot)(2)(L-IQ) Cl] whose structural and magnetic properties are described.

机译：MnCl2与非纯配体H3L的反应产生了前所未有的混合价三核配合物[（MnMnMnIV）-Mn-II-Mn-III（L）（L中心点）（2）（L-IQ）Cl]描述了其结构和磁性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2006年第18期|共3页
作者
Mukherjee C; Weyhermuller T; Wieghardt K; Chaudhuri P;
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正文语种 eng
中图分类无机化学;
关键词
O-IMINOBENZOSEMIQUINONATO COMPLEXES; OXYGEN-EVOLVING COMPLEX; PHOTOSYSTEM-II; ELECTRONIC-STRUCTURE; MANGANESE CLUSTER; OXIDATION-STATES; GROUND-STATE; DINUCLEAR; WATER; MONONUCLEAR;

机译：O-亚氨基苯并半醌络合物;放氧络合物;光体系II;电子结构;锰簇;氧化态;基态;粒径;水;单核;

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1. A trinuclear complex containing (MnMnMnIV)-Mn-II-Mn-III, radicals, quinone and chloride ligands potentially relevant to PSII [J] . Mukherjee C, Weyhermuller T, Wieghardt K, Dalton transactions: An international journal of inorganic chemistry . 2006,第18期

机译：包含（MnMnMnIV）-Mn-II-Mn-III，自由基，醌和氯化物配体的三核配合物
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A trinuclear complex containing (MnMnMnIV)-Mn-II-Mn-III, radicals, quinone and chloride ligands potentially relevant to PSII

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