Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization

Takuya Kochi; Kenji Yoshimura; Kyoko Nozaki

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Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization

机译：具有膦磺酸盐配体的阴离子甲基钯配合物的合成及其在烯烃聚合中的活性

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Reaction of diarylphosphinobenzene-2-sulfonic acids with tertially amines,followed by addition of [PdMeCl(cod)],provided anionic methylpalladium(II)complexes with bidentate phosphine-sulfonate ligands,which show high activity for copolymerization of ethylene with methyl acrylate.Olefin polymerization with late transition-metal complexes has attracted much interest due to their lower oxophilicity relative to early transition metals,and many catalysts have been developed to polymerize various olefins and to copolymerize non-polar olefins with carbon monoxide or with polar olefins.

机译：二芳基膦基苯-2-磺酸与叔胺的反应，接着加入[PdMeCl（cod）]，制得的阴离子甲基钯（II）配合物具有二齿膦-磺酸盐配体，对乙烯与丙烯酸甲酯的共聚反应具有高活性。由于与早期过渡金属相比，低过渡金属具有较低的亲氧性，因此与晚期过渡金属配合物的聚合反应引起了人们的极大兴趣，并且已经开发出许多催化剂来聚合各种烯烃并使非极性烯烃与一氧化碳或极性烯烃共聚。

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《Dalton transactions: An international journal of inorganic chemistry》 |2006年第1期|共3页
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Takuya Kochi; Kenji Yoshimura; Kyoko Nozaki;
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1. Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization [J] . Takuya Kochi, Kenji Yoshimura, Kyoko Nozaki Dalton transactions: An international journal of inorganic chemistry . 2006,第1期

机译：具有膦磺酸盐配体的阴离子甲基钯配合物的合成及其在烯烃聚合中的活性
2. Titanium complexes bearing a hemilabile heteroscorpionate ligand: Synthesis, reactivity, and olefin polymerization activity [J] . Milione S, Bertolasi V, Cuenca T, Organometallics . 2005,第21期

机译：带有半不稳定杂蝎子配体的钛配合物：合成，反应性和烯烃聚合活性
3. Synthesis and Reactivity of Methylpalladium Complexes Bearing a Partially Saturated IzQO Ligand [J] . Akita Shumpei, Nakano Ryo, Ito Shingo, Organometallics . 2018,第14期

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4. Synthesis of Linear Polyolefins Using Palladium Complexes Bearing Phosphine-Sulfonate Bidentate Ligands [C] . Takuya Kochi, Shusuke Noda, Kenji Yoshimura Symposium on Organometallic Chemistry . 2006

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5. Synthesis, reactivity, and olefin polymerization characteristics of palladium complexes bearing an ortho-phosphino-sulfonate ancillary ligand [D] . DeFoe, Jacqueline J. 2011

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6. New Molybdenum(II) Complexes with α-Diimine Ligands: Synthesis Structure and Catalytic Activity in Olefin Epoxidation [O] . Maria Vasconcellos-Dias, João Marreiros, Rita Sales, 2019

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7. Ethylene-bridged tetramethylcyclopentadienylamide titanium complexes: Ligand synthesis and olefin polymerization properties:Ligand Synthesis and Olefin Polymerization Properties [O] . van Leusen D., Beetstra D.J., Hessen B., 2000

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8. Preparation and Reactions of Tantalum Alkylidene Complexes Containing Bulky Phenoxide or Thiolate Ligands. Controlling Ring-Opening Metathesis Polymerization Activity and Mechanism Through Choice of Anionic Ligand [R] . Wallace, K. C., Liu, A. H., Dewan, J. C., 1988

机译：含大量酚盐或硫醇盐配体的亚钽基亚砜配合物的制备及反应。通过选择阴离子配体控制开环易位聚合活性及机理

Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization

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