Novel (n+1+1) cycloaddition reactions; the formation of cyclic tetraphosphonium dications with four linked phosphorus atoms and an organic backbone

Boyall AJ; Dillon KB; Howard JAK; Monks PK; Thompson AL

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Novel (n+1+1) cycloaddition reactions; the formation of cyclic tetraphosphonium dications with four linked phosphorus atoms and an organic backbone

机译：新的（n + 1 + 1）个环加成反应;形成具有四个连接的磷原子和一个有机主链的环状四磷鎓盐

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In the presence of SnCl2, a novel cycloaddition of two moles of R'PCl2 (R' = Et or Ph) to a diphosphane has been achieved, forming a cyclic dication with four linked phosphorus atoms and an organic backbone; two of these species have been characterised by single-crystal X-ray diffraction, and the mechanism of the reaction has been established.

机译：在SnCl2的存在下，已经实现了两摩尔R'PCl2（R'= Et或Ph）与二膦的新型环加成反应，形成了具有四个连接的磷原子和一个有机骨架的环状指示。这些物种中的两个已经通过单晶X射线衍射表征，并且已经建立了反应机理。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第14期|共3页
作者
Boyall AJ; Dillon KB; Howard JAK; Monks PK; Thompson AL;
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正文语种 eng
中图分类无机化学;
关键词
MOLECULAR-STRUCTURE; TRIPHOSPHENIUM IONS; CRYSTAL; CHEMISTRY; IODIDE; CATION;

机译：分子结构;TRI离子;晶体;化学;碘化物;阳离子;

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1. Novel (n+1+1) cycloaddition reactions; the formation of cyclic tetraphosphonium dications with four linked phosphorus atoms and an organic backbone [J] . Boyall AJ, Dillon KB, Howard JAK, Dalton transactions: An international journal of inorganic chemistry . 2007,第14期

机译：新的（n + 1 + 1）个环加成反应;形成具有四个连接的磷原子和一个有机主链的环状四磷鎓盐
2. Degradation and modification of metallaboranes Part 3. Reactions of the hexaborane(10) analogue nido-(PPh3)(2)(CO)OsB5H9 with bidentate phosphines containing a rigid backbone: formation of linked cluster systems [J] . McQuade P., Winter REK., Barton L. Journal of Organometallic Chemistry . 2003,第1a2期

机译：金属硼烷的降解和修饰第3部分。六硼烷（10）类似物nido-（PPh3）（2）（CO）OsB5H9与含有刚性骨架的双齿膦的反应：形成连接簇系统
3. Reactions of cerium atoms and dicerium molecules with CO: Formation of cerium carbonyls and photoconversion to CO-activated insertion molecules [J] . Zhou MF, Jin X, Li J The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第34期

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4. REACTIVITY-STRUCTURE BASED RATE ESTIMATION RULES FOR ALKYL RADICAL H- ATOM SHIFT AND ALKENYL RADICAL CYCLOADDITION REACTIONS [C] . Kun Wang, Stephanie M. Villano, Anthony M. Dean ACS National Meeting Exhibition . 2015

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5. Synthesis of functionalized organic molecules using copper catalyzed cyclopropanation, atom transfer radical reactions and sequential azide-alkyne cycloaddition [D] . Ricardo, Carolynne Lacar 2011

机译：铜催化环丙烷化，原子转移自由基反应和叠氮化物-炔烃环加成反应合成功能化有机分子
6. Prediction of reacting atoms for the major biotransformation reactions of organic xenobiotics [O] . Anastasia V. Rudik, Alexander V. Dmitriev, Alexey A. Lagunin, 2016

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7. A multinuclear NMR study of the cycloaddition reaction of SNSAsF6 with tert-butylphosphaacetyline (CH3)3CCP leading to the 5-tert-butyl-1,3,2,4-dithiazaphospholium cation; a preliminary account of the novel exchange of a cyclic phosphorus by nitrogen in the reaction of with azide N3− leading to 5-tert-butyl-1,3,2,4-dithiadiazolyl [O] . Simon Parsons, Jack Passmore, Xiaoping Sun, 1995

机译：叔丁基膦酰基（CH3）3CCP与叔丁基膦酰基 - 1,3,2,4-二亚亚代亚代阳离子的叔丁基膦酰基乙酰乙基（CH3）3CCP的循环加油反应的多核NMR研究。用氮气与叠氮化物N3-导致5-叔丁基-1,3,2,4-二唑基的反应中氮的新型循环磷交换的初步叙述
8. Controlled Synthesis of Organic-Inorganic Polymers that Possess a Backbone of Phosphorus and Nitrogen Atoms [R] . Allcock, H. R. 1981

机译：具有磷和氮原子骨架的有机 - 无机聚合物的可控合成

Novel (n+1+1) cycloaddition reactions; the formation of cyclic tetraphosphonium dications with four linked phosphorus atoms and an organic backbone

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