Closed-pore crystal capable of adsorbing CO2 onto isolated cavities generated by disorderly mixing of substituents on host skeleton

Satoshi Takamizawa; Masa-aki Kohbara

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Closed-pore crystal capable of adsorbing CO2 onto isolated cavities generated by disorderly mixing of substituents on host skeleton

机译：能够将CO2吸附到由主体骨架上的取代基无序混合产生的孤立腔中的闭孔晶体

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A single crystal adsorbent,[Rh(II)2(bza)4(2,3-empyz)]_n(2,3-empyz = 2-ethyl-3-methylpyrazine)(1),was synthesized by self-assembly reaction of a Rh2 benzoate complex and substituted pyrazine linker.The compound consists of one-dimensional zigzag chains,which generated a closed-pore structure without channels.The cavities were statistically generated by the static disorder of substituents on pyrazine and are separated by long intervals within the crystal.The property of CO2 absorption was characterized in this closed-pore system.The CO2 inclusion structure was determined by single-crystal X-ray diffraction measurements.These studies suggest that CO2 molecules were adsorbed and diffused in the nonporous crystal with the isolated cavities.

机译：通过自组装反应合成了单晶吸附剂[Rh（II）2（bza）4（2,3-empyz）] _ n（2,3-empyz = 2-乙基-3-甲基吡嗪）（1）化合物由一维之字形链组成，形成无孔的闭孔结构。空穴是由吡嗪上的取代基的静态无序统计生成的，并在内部以长间隔隔开在该闭孔系统中表征了CO2的吸收特性。通过单晶X射线衍射测量确定了CO2的夹杂物结构。空腔。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第33期|共6页
作者
Satoshi Takamizawa; Masa-aki Kohbara;
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正文语种 eng
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1. Closed-pore crystal capable of adsorbing CO2 onto isolated cavities generated by disorderly mixing of substituents on host skeleton [J] . Satoshi Takamizawa, Masa-aki Kohbara Dalton transactions: An international journal of inorganic chemistry . 2007,第33期

机译：能够将CO2吸附到由主体骨架上的取代基无序混合产生的孤立腔中的闭孔晶体
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Closed-pore crystal capable of adsorbing CO2 onto isolated cavities generated by disorderly mixing of substituents on host skeleton

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