eta~1-2-Pyrone metal carbonyl complexes as CO-releasing molecules(CO-RMs):A delicate balance between stability and CO liberation

Ian J.S.Fairlamb; Jason M.Lynam; Benjamin E.Moulton

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eta~1-2-Pyrone metal carbonyl complexes as CO-releasing molecules(CO-RMs):A delicate balance between stability and CO liberation

机译：eta〜1-2-吡喃金属羰基配合物作为CO释放分子（CO-RMs）：稳定性与CO释放之间的微妙平衡

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An evaluation of the CO releasing ability of iron(II)and molybdenum(II)complexes has facilitated the discovery of the most rapid CO releaser,namely [Mo(CO)3(eta~5-C5H5)(eta~1-{O}-C{=O}-O-CMe=CH-COMe=CBr)]BF4(CORM-F10),reported to date.The rate of CO release is related to the overall solution phase stability of the transition metal carbonyl complex.The cytotoxity and vasodilatory properties of CORM-F10 have been determined.

机译：铁（II）和钼（II）配合物的CO释放能力的评估促进了最快的CO释放剂的发现，即[Mo（CO）3（eta〜5-C5H5）（eta〜1- {O } -C {= O} -O-CMe = CH-COMe = CBr）] BF4（CORM-F10），到目前为止。CO的释放速率与过渡金属羰基配合物的整体溶液相稳定性有关。已确定CORM-F10的细胞毒性和血管舒张特性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第33期|共3页
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Ian J.S.Fairlamb; Jason M.Lynam; Benjamin E.Moulton;
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1. eta~1-2-Pyrone metal carbonyl complexes as CO-releasing molecules(CO-RMs):A delicate balance between stability and CO liberation [J] . Ian J.S.Fairlamb, Jason M.Lynam, Benjamin E.Moulton Dalton transactions: An international journal of inorganic chemistry . 2007,第33期

机译：eta〜1-2-吡喃金属羰基配合物作为CO释放分子（CO-RMs）：稳定性与CO释放之间的微妙平衡
2. Photoactivated Functionizable Tetracarbonyl(phenylpyridine)manganese(I) Complexes as CO-Releasing Molecules: A Direct Suzuki-Miyaura Cross-Coupling on a Thermally Stable CO-RM [J] . Ward Jonathan S., Bray Joshua T. W., Aucott Benjamin J., European journal of inorganic chemistry . 2016,第31期

机译：作为CO释放分子的光活化功能化四羰基（苯基吡啶）锰（I）配合物：在热稳定CO-RM上的直接Suzuki-Miyaura交叉偶联
3. New types of CO-releasing molecules (CO-RMs), based on iron dithiocarbamate complexes and [Fe(CO) _3I(S _2COEt)] [J] . Hewison L., Crook S.H., Mann B.E., Organometallics . 2012,第16期

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4. Encapsulation of Transition Metal Carbonyl Complexes in Self-Assembled Cages and the Photoreaction [C] . Yasuhiro Kobavashi, Masaki Kawano, Michito Yoshizawa, Symposium on Organometallic Chemistry . 2004

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机译：二烷基氨基磷酸金属羰基化合物。 2.来自锰和羰基钴与双（二异丙基氨基）膦的反应的双（二异丙基氨基）膦基和（二异丙基氨基）亚膦基金属羰基配合物

eta~1-2-Pyrone metal carbonyl complexes as CO-releasing molecules(CO-RMs):A delicate balance between stability and CO liberation

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