Isolation and characterisation of a novel thermally stable octahedral bicarbonate complex of bis(2-picolylamine)copper(II):identification of rare monodentate coordination

Chirantan Roy Choudhury; Subrata Kumar Dey; Samiran Mitra; Volker Gramlich

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Isolation and characterisation of a novel thermally stable octahedral bicarbonate complex of bis(2-picolylamine)copper(II):identification of rare monodentate coordination

机译：双（2-甲基吡啶胺）铜（II）的新型热稳定八面体碳酸氢盐配合物的分离与表征：稀有单齿配位的鉴定

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A novel bicarbonate complex,[Cu(C_5H_4NCH_2NH_2)_2-(OCO_2H)_2](1),has been synthesised under controlled pH and characterised by IR,UV-Vis spectroscopy,magnetic moment and thermal analysis;the coordination environment around the metal centre is elongated octahedral with two chelated bidentate amines in the square plane and the axial sites are occupied by two monodentate bicarbonate ligands.

机译：在控制pH值的条件下，合成了一种新型的碳酸氢盐配合物[Cu（C_5H_4NCH_2NH_2）_2-（OCO_2H）_2]（1），并通过IR，UV-Vis光谱，磁矩和热分析表征了金属中心周围的配位环境。是细长的八面体，在正方形平面上带有两个螯合的二齿胺，轴向位点被两个单齿碳酸氢盐配体占据。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第6期|共2页
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Chirantan Roy Choudhury; Subrata Kumar Dey; Samiran Mitra; Volker Gramlich;
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1. Isolation and characterisation of a novel thermally stable octahedral bicarbonate complex of bis(2-picolylamine)copper(II):identification of rare monodentate coordination [J] . Chirantan Roy Choudhury, Subrata Kumar Dey, Samiran Mitra, Dalton transactions: An international journal of inorganic chemistry . 2003,第6期

机译：双（2-甲基吡啶胺）铜（II）的新型热稳定八面体碳酸氢盐配合物的分离与表征：稀有单齿配位的鉴定
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7. Octahedral Bis(2-picolylamine) Complexes of Cobalt(III). Preparations and Partial Structural Assignments of Two Series of Isomers. [O] . Kirsten Michelsen, Bjarne Kimland, Sven-Olof Almqvist, 1972

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机译：镍和铜化合物的晶体结构第一部分2.2'-亚氨基（乙酰氨基）第二部分正二甲基铜（Ⅱ）配合物的两个双配合物

Isolation and characterisation of a novel thermally stable octahedral bicarbonate complex of bis(2-picolylamine)copper(II):identification of rare monodentate coordination

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